Hongwei Jin

Name: 金红卫; Jin, HongWei

Organization: Zhejiang University of Technology , China

Department: State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology

Title: Associate Professor(PhD)

Chemicals
References

Synthesis of dibenzopyranones and pyrazolobenzopyranones through copper(0)/Selectfluor system-catalyzed double CH activation/oxygen insertion of 2-arylbenzaldehydes and 5-arylpyrazole-4-carbaldehydes

Co-reporter:Jian Zhang, Dongdong Shi, Haifeng Zhang, Zheng Xu, Hanyang Bao, Hongwei Jin, Yunkui Liu

Tetrahedron 2017 Volume 73(Issue 2) pp:154-163

Publication Date(Web):12 January 2017

DOI:10.1016/j.tet.2016.11.069

A mild and efficient protocol for the synthesis of dibenzopyranones and pyrazolobenzopyranones was developed involving a copper(0)/Selectfluor system-catalyzed double CH activation/oxygen insertion of 2-arylbenzaldehydes and 5-arylpyrazole-4-carbaldehydes. Preliminary mechanistic studies suggest that both water and dioxygen act as the oxygen source in the formation of pyranone scaffolds.

Copper(0)/Selectfluor System-Promoted Oxidative Carbon–Carbon Bond Cleavage/Annulation of o-Aryl Chalcones: An Unexpected Synthesis of 9,10-Phenanthraquinone Derivatives

Co-reporter:Hanyang Bao, Zheng Xu, Degui Wu, Haifeng Zhang, Hongwei Jin, and Yunkui Liu

The Journal of Organic Chemistry 2017 Volume 82(Issue 1) pp:109-118

Publication Date(Web):December 2, 2016

DOI:10.1021/acs.joc.6b02212

A general and efficient protocol for the synthesis of 9,10-phenanthraquinone derivatives has been successfully developed involving a copper(0)/Selectfluor system-promoted oxidative carbon–carbon bond cleavage/annulation of o-aryl chalcones. A variety of substituted 9,10-phenanthraquinones were synthesized in moderate to good yields under mild reaction conditions.

Synthesis of Polysubstituted Pyrroles from Activated Alkynes and N-Propargylamines through Base-Catalyzed Cascade Reaction

Co-reporter:Jianquan Weng;Yong Chen;Binjie Yue;Meng Xu

European Journal of Organic Chemistry 2015 Volume 2015( Issue 14) pp:3164-3170

Publication Date(Web):

DOI:10.1002/ejoc.201500166

Abstract

A novel K₃PO₄-catalyzed synthesis of polysubstituted pyrroles by a Michael addition/alkyne carbocyclization of activated alkynes and N-propargylamines has been developed. This transition-metal-free cascade process represents an environmental friendly and efficient way to construct polysubstituted pyrroles in good yields. Catalyzed by CsF, a Michael addition/aza-Claisen rearrangement/cyclization sequential process has been achieved to selectively synthesize pyrroles in moderate yields.