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Tao Wang

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Organization: Shenzhen Graduate School of Peking University
Department: School of Chemical Biology and Biotechnology
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Ag-Carbenoid-Initiated Catalytic Hydration Cascades: Rapid Construction of Functionalized Bicyclo[3.3.1]nonanes
Co-reporter:Lu Wang, Shunyou Cai, Xiangyou Xing, Ying Gao, Tao Wang, and David Zhigang Wang
Organic Letters 2013 Volume 15(Issue 10) pp:2362-2365
Publication Date(Web):May 2, 2013
DOI:10.1021/ol4006954
Remarkable Ag-carbenoid-initiated enone cyclopropanation–hydrolytic fragmentation–competitive 1,2-vs-1,4 addition reaction cascades were uncovered on a range of propargylic esters tethered to cyclohexadienones, leading to the highly efficient and stereospecific construction of densely functionalized bicyclo[3.3.1]nonanes under mild conditions.
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