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Jay Dunsford

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Organization: University of Manchester
Department: School of Chemistry, Main Building
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Pd–PEPPSI-Type Expanded Ring N-Heterocyclic Carbene Complexes: Synthesis, Characterization, and Catalytic Activity in Suzuki–Miyaura Cross Coupling
Co-reporter:Jay J. Dunsford and Kingsley J. Cavell
Organometallics 2014 Volume 33(Issue 11) pp:2902-2905
Publication Date(Web):May 22, 2014
DOI:10.1021/om5003107
The synthesis and characterization of the new six- and seven-membered Pd–PEPPSI-type N-heterocyclic carbene (NHC) complexes 3 and 4 is described. Complexes of the general formula [Pd(NHC)(3ClPy)Cl2] (NHC = 6- or 7-Mes, 3ClPy = 3-chloropyridine) are accessed via the oxidation of the well-defined parent palladium(0) complexes 1 and 2. Complexes 3 and 4 have been employed in Suzuki–Miyaura cross-coupling and catalytic dehalogenation of a range of aryl halide substrates.
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