Scanning electron microscopes (SEMs) require a high vacuum environment to generate and shape an electron beam for imaging; however, the vacuum conditions greatly limit the nature of specimens that can be examined. From a purely scattering physics perspective, it is not necessary to place the specimen inside the vacuum chamber—the mean free paths (MFPs) for electron scattering in air at typical SEM beam voltages are 50–100 μm. This is the idea behind the airSEM, which removes the specimen vacuum chamber from the SEM and places the sample in air. The thickness of the gas layer is less than a MFP from an electron-transparent window to preserve the shape and resolution of the incident beam, resulting in comparable imaging quality to an all-vacuum SEM. Present silicon nitride windows scatter far more strongly than the air gap and are currently the contrast and resolution limiting factor in the airSEM. Graphene windows have been used previously to wrap or seal samples in vacuum for imaging. Here we demonstrate the use of a robust bilayer graphene window for sealing the electron optics from the room environment, providing an electron transparent window with only a 2% drop in contrast. There is a 5-fold-increase in signal/noise ratio for imaging compared to multi-MFP-thick silicon nitride windows, enabling high contrast in backscattered, transmission, and surface imaging modes for the new airSEM geometry.Keywords: AirSEM; electron scattering; graphene; SEM; STEM;

Unlike in linear nanostructures, photocurrent generated in single-layer graphene (SLG) is expected to display two-dimensional characteristics. This allows the investigation of carrier dynamics, in relation to several spatially varying factors (such as the location of photocurrent generation and collection) and the overall electron band configuration of the SLG. In this letter, we use scanning photocurrent microscopy to investigate the spatial mapping of photocurrent generation and collection in SLG in a multielectrode geometry. A strong electric field near metal-graphene contacts leads to efficient photocurrent generation, resulting in >30% efficiency for electron−hole separation. The polarity and magnitude of contact photocurrent are used to study the band alignment and graphene electrical potential near contacts, from which it is shown that there exist large-scale spatial variations in graphene electric potential. Our measurements with a multielectrode device configuration reveal that photocurrent is distributed with a clear directional dependence among different collector electrodes. In the same measurement scheme, we also determine the majority carrier in graphene under different gate conditions by imaging the thermocurrent generated by laser-induced heating of electrodes.

We report electroluminescence (EL) measurements carried out on three-terminal devices incorporating individual n-type CdSe nanowires. Simultaneous optical and electrical measurements reveal that EL occurs near the contact between the nanowire and a positively biased electrode or drain. The surface potential profile, obtained by using Kelvin probe microscopy, shows an abrupt potential drop near the position of the EL spot, while the band profile obtained from scanning photocurrent microscopy indicates the existence of an n-type Schottky barrier at the interface. These observations indicate that light emission occurs through a hole leakage or an inelastic scattering induced by the rapid potential drop at the nanowire−electrode interface.