YanHong Hu

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Name: 扈艳红; Hu, YanHong
Organization: East China University of Science and Technology , China
Department: Key Laboratory for Specially Functional Polymers and Related Technology of Ministry of Education
Title: Associate Professor(PhD)
Co-reporter:Qing Zhao;Xingyi Wang
Journal of Applied Polymer Science 2016 Volume 133( Issue 3) pp:
Publication Date(Web):
DOI:10.1002/app.42875

ABSTRACT

Intumescent-flame-retarded polypropylene (PP-IFR) composites were prepared by the incorporation of methyl hydrogen siloxane treated ammonium polyphosphate and dipentaerythritol in a twin-screw extruder. The effects of zeolite (Z), multiwalled carbon nanotubes (CNTs), and maleic anhydride grafted polypropylene on the flame retardancy, mechanical properties, and thermal stability of PP-IFR were investigated. The addition of Z and CNT promoted the flame retardancy of PP-IFR, and the highest limited oxygen index was 35.6%, obtained on PP-M-IFR-2–Z, for which the heat-release rate, total heat release, and smoke production rate based on cone calorimetry analyses decreased by 45.0, 51.0, and 66.3%, respectively, in comparison with those values of the PP-IFR composites. Additionally, scanning electron microscopy analyses showed that there was a good interface interaction between the polypropylene matrix and additives. The flexural, tensile, and impact strengths of the PP-IFR composites were improved significantly with the incorporation of CNT. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016, 133, 42875.

Co-reporter:Qing Zhao;Xing-yi Wang 王幸宜;Yan-hong Hu 扈艳红
Chinese Journal of Polymer Science 2015 Volume 33( Issue 10) pp:1359-1372
Publication Date(Web):2015 October
DOI:10.1007/s10118-015-1685-0
Polyimides (PIs) with various molecular weights synthesized via the reaction of aromatic diamine monomer containing tert-butyl groups with aromatic dianhydride were highly soluble in common organic solvents and some epoxy resins at room temperature. These PIs can be incorporated in the absence of organic solvent into epoxy resin E51 with the loading below 2 wt% forming EP-PI composites. No phase separation is observed by SEM on cryogenically fractured surfaces of EP-PI composites. The PI can improve mechanical properties, especially impact strength. Adding 2 wt% PI-1.5W, the impact strength reaches to 55 kJ/m2 with the increase in tensile and flexural strengths by 14% and 3%, respectively. SEM analyses for the fracture surface suggest that PI reduces the crosslink density, improves the plasticity of epoxy resin and changes the mode of fracture from fragile to ductile. Moreover, the glass transition temperature of EP-PI composites was found to increase to a significant extent.
Poly[oxy(methylsilylene)],a-(trimethylsilyl)-w-[(trimethylsilyl)oxy]-