Yasushi Obora - Cochemist

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Yasushi Obora

Name:

Organization: Kansai University

Department: Department of Chemistry and Materials Engineering, Faculty of Chemistry, Materials and Bioengineering, High Technology Research Center, and ORDIST

Title:

Chemicals
References

Iridium-Catalyzed Coupling Reaction of Primary Alcohols with 1-Aryl-1-propynes Leading to Secondary Homoallylic Alcohols

Co-reporter:Yasushi Obora, Shintaro Hatanaka and Yasutaka Ishii

Organic Letters 2009 Volume 11(Issue 15) pp:3510-3513

Publication Date(Web):July 13, 2009

DOI:10.1021/ol901366q

We report iridium-catalyzed coupling of 2-alkynes such as 1-aryl-1-propynes with primary alcohols leading to secondary homoallylic alcohols as products. This reaction involves an iridium-catalyzed novel catalytic transformation of 2-alkynes and primary alcohols through the formation of hydrido(π-allyl)iridium as a possible key intermediate.

1-Octanone, 2-methyl-1-phenyl-

1-Octanone, 2-methyl-1-phenyl-

CAS:132719-12-1

1-Octanone, 2-methyl-1-phenyl-

Benzamide, N-(1,2,2-trimethylpropyl)-, (±)-

Benzamide, N-(1,2,2-trimethylpropyl)-, (±)-

CAS:114459-70-0

Benzamide, N-(1,2,2-trimethylpropyl)-, (±)-

2-methyl-1-naphthalen-2-ylpropan-1-one

2-methyl-1-naphthalen-2-ylpropan-1-one

CAS:107574-57-2

2-methyl-1-naphthalen-2-ylpropan-1-one

1-Propanone, 1-(4-methoxyphenyl)-2-methyl-3-phenyl-

1-Propanone, 1-(4-methoxyphenyl)-2-methyl-3-phenyl-

1-Propanone, 1-(4-methoxyphenyl)-2-methyl-3-phenyl-

Benzamide,N-[1-(4-methylphenyl)ethyl]-

Benzamide,N-[1-(4-methylphenyl)ethyl]-

Benzamide,N-[1-(4-methylphenyl)ethyl]-

Silane, [(2E)-3-cyclohexyl-2-propenyl]trimethyl-

Silane, [(2E)-3-cyclohexyl-2-propenyl]trimethyl-

Silane, [(2E)-3-cyclohexyl-2-propenyl]trimethyl-

SILANE, TRIMETHYL[(2E)-4-PHENYL-2-BUTENYL]-

SILANE, TRIMETHYL[(2E)-4-PHENYL-2-BUTENYL]-

SILANE, TRIMETHYL[(2E)-4-PHENYL-2-BUTENYL]-

1-Decanone, 2-methyl-1-phenyl-

1-Decanone, 2-methyl-1-phenyl-

1-Decanone, 2-methyl-1-phenyl-

Benzamide, N-(1-methyl-2-phenylethyl)-, (±)-

Benzamide, N-(1-methyl-2-phenylethyl)-, (±)-

Benzamide, N-(1-methyl-2-phenylethyl)-, (±)-

Silane, 2-cyclohepten-1-yltrimethyl-

Silane, 2-cyclohepten-1-yltrimethyl-

Silane, 2-cyclohepten-1-yltrimethyl-