Bin Yang

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Name: 杨斌
Organization: Anhui University , China
Department: College of Chemistry and Chemical Engineering
Title: Associate Professor(PhD)

TOPICS

Co-reporter:Bin Yang;Lei Hu;Ru Xia;Fang Chen;Shu-Chun Zhao;Yan-Li Deng
Macromolecular Research 2016 Volume 24( Issue 1) pp:74-82
Publication Date(Web):2016 January
DOI:10.1007/s13233-016-2015-7
In this study, nanofillers composed of hydroxylated carbon nanotubes (h-CNT), carbon nanotubes (CNT) and graphene (GR) were separately added into the dynamically-vulcanized polypropylene (PP)/ethylene-propylenediene monomer (EPDM) blend. Differential scanning calorimetry (DSC), wide-angle X-ray diffraction (WAXD) and electrical resistivity measurements were employed to study the effect of nanofillers on the melt behavior, non-isothermal crystallization behavior and electrical conductivity of the prepared composites. WAXD results showed that h-CNT had a better induction effect of β-PP in the nanocomposites. The sequence of the activity in inducing the formation of β-PP was h-CNT>GR>CNT. However, the total crystallinity of the nanocomposites nearly remained constant. Non-isothermal crystallization kinetic analysis indicated that the presence of nanofillers improved the crystallization rate of the nanocomposites. The consequence of nucleation activity was as follows: CNT>GR>h-CNT. Although EPDM hindered the macromolecular motion of PP, interestingly it could increase the crystallization rate to an extent. Besides, the influence of nanofillers on enhancing the conductive property of the nanocomposites can be ranked as follow: CNT>GR>h-CNT.
Co-reporter:Bin Yang, Ru Xia, Ji-Bin Miao, Jia-Sheng Qian, Ming-Bo Yang, Peng Chen
Polymer Testing 2013 Volume 32(Issue 2) pp:202-208
Publication Date(Web):April 2013
DOI:10.1016/j.polymertesting.2012.10.004
The largest part of an injection molding cycle is occupied by melt cooling, which significantly influences the properties of the final parts, especially for crystalline polymers which undergo both solidification and crystallization processes simultaneously. Based on non-isothermal crystallization characterization, solidification kinetics of high density polyethylene was investigated via an in-situ measurement of in-cavity temperature profiles throughout the injection molding process. Existence of the turning point in the cooling curve of ln θ vs. ln t, which can be employed for estimation of the minimum cooling time, was for the first time validated experimentally. Good agreement was achieved through the comparison between experimental observations and theoretical predictions using the enthalpy transformation method (ETM). The present study will be instructive for the optimization of processing variables, and gives insight into the formation of various crystalline structures in injection molded articles, as well as forecast of cooling time of injection moldings of crystalline polymers.
Co-reporter:Bin Yang;Ji-Bin Miao;Kai Min;Ru Xia;Jia-Sheng Qian ;Xing Wang
Journal of Applied Polymer Science 2013 Volume 128( Issue 3) pp:1922-1929
Publication Date(Web):
DOI:10.1002/app.38376

Abstract

It was widely established that many end-use properties of the final parts are considerably affected by the macromolecular hierarchical structures formed during the cooling stage of injection molding, especially for crystalline polymers which undergo both solidification and crystallization processes simultaneously. Enthalpy transformation method (ETM) has been demonstrated to give the reasonable descriptions of the temperature profiles for real processing operations (e.g., injection molding, gas-assisted injection molding, and compression molding, etc.) in our previous work. However, to observe the phase-change plateau, where rapid cooling rate is imposed, is not easy in traditional treatments using the enthalpy approach. In this work, “modified cooling curves” (i.e., temperature versus time, plotted in logarithmic scale) at various locations in the mold cavity were found to show similar trend with an obvious turning point indicating the occurrence of phase transition. Mold temperature is more effective in controlling the cooling rate than melt temperature. Turing point of the cooling curves in the plot of ln θ vs. ln t can be used to estimate the minimum cooling time of the injection molding of crystalline polymers. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013

5-Decene-1,3,7,9-tetrayne
NONA-1,3,5,7-TETRAYNE
1,2,3,4-Pentatetraenyl
3-Decene-1,5,7,9-tetrayne
2-Butynyl
2-Propynyl, 1-ethynyl-
PENT-1-EN-4-YNE
2-ETHYNYL-1H-INDENE