Martin Pope

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Name: Pope, Martin
Organization: New York University , USA
Department: Chemistry Department
Title: (PhD)

TOPICS

Co-reporter:Martin Pope, Henry C Brenner
Synthetic Metals 2004 Volume 141(1–2) pp:185-192
Publication Date(Web):18 March 2004
DOI:10.1016/j.synthmet.2003.09.020
Geminate recombination in the presence of an inhomogeneous electric field is analyzed theoretically. The model fields employed exhibit cylindrical and spherical symmetry. It is shown that when the spatial variation of the geminate pair concentration and that of the field intensity are comparable, there are significant differences from the response observed in homogeneous electric fields.
Co-reporter:Martin Pope, Bastiaan J Braams, Henry C Brenner
Chemical Physics 2003 Volume 288(2–3) pp:105-112
Publication Date(Web):15 March 2003
DOI:10.1016/S0301-0104(02)01026-1

Abstract

Hypothetical experiments are described in which excitons diffuse in systems that exhibit cylindrical or spherical symmetry. A line source of excitation will be assumed at the axis of the cylinder, and a point source at the center of the sphere. Diffusion equations that are appropriate for these geometries are set up and solved in closed form for the boundary conditions of complete quenching of excitons or complete reflection of excitons. Steady state and transient conditions are treated. Based upon assumed values of the diffusion lengths, plots are constructed of the spatial distribution of excitons. For a wide range of assumed values of the diffusion lengths, these values can be recovered from an analysis of the resultant diffusion currents and their absorption coefficient dependence to within a few percent.

5-methyl-1,2,3,4-tetrahydrochrysene-1,2,3,4-tetrol
9,10-EPOXY-7,8-DIHYDROXY-7,8,9,10-TETRAHYDRO-5-METHYLCHRYSENE
1-(pyren-1-yl)ethane-1,2-diol
2-pyren-1-yloxirane
Benzo[a]pyrene-7,8,9,10-tetrol,7,8,9,10-tetrahydro-
Benzo[10,11]chryseno[3,4-b]oxirene-7,8-diol,7,8,8a,9a-tetrahydro-, (7R,8S,8aS,9aR)-rel-
7,8,8a,9a-Tetrahydrobenzo[1,12]tetrapheno[10,11-b]oxirene-7,8-diol
ACETYLENE
10-hydroxyanthracen-9(10H)-one
Allyl isothiocyanate