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Birgit Esser

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Organization: University of Bonn , Germany
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Title: (PhD)

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Synthesis of Isoindoles by One-Electron Reductions of Dibenzo[1,4]diazocines
Co-reporter:Marcel Bovenkerk
European Journal of Organic Chemistry 2015 Volume 2015( Issue 4) pp:775-785
Publication Date(Web):
DOI:10.1002/ejoc.201403315

Abstract

A synthetic protocol to isoindoles is reported through one-electron reductions of dibenzo[1,4]diazocines. The utility of the approach has been demonstrated through the synthesis of six novel isoindole derivatives. Photophysical measurements revealed emissions between 440 and 460 nm. A reaction mechanism, supported by experimental results and quantum chemical calculations, is postulated.

2-BENZOYL-5-BROMOBENZOIC ACID
2-BENZOYL-5-BROMOBENZOIC ACID
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2-BENZOYL-5-BROMOBENZOIC ACID
Benzoic acid, 2-benzoyl-4-bromo-
Benzoic acid, 2-benzoyl-4-bromo-
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Benzoic acid, 2-benzoyl-4-bromo-
1(3H)-ISOBENZOFURANONE, 5-BROMO-3-PHENYL-
1(3H)-ISOBENZOFURANONE, 5-BROMO-3-PHENYL-
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1(3H)-ISOBENZOFURANONE, 5-BROMO-3-PHENYL-
2,2'-Spirobi[2H-indene]-1,1',3,3'-tetrone
2,2'-Spirobi[2H-indene]-1,1',3,3'-tetrone
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2,2'-Spirobi[2H-indene]-1,1',3,3'-tetrone
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Methanone, (4-methoxy-1,2-phenylene)bis[phenyl-
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Methanone, (4-methoxy-1,2-phenylene)bis[phenyl-
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Benzoic acid, [(2-hydroxy-4-methoxyphenyl)phenylmethylene]hydrazide
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Benzoic acid, [(2-hydroxy-4-methoxyphenyl)phenylmethylene]hydrazide
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Dibenzo[b,f][1,4]diazocine, 8-methyl-6,11-diphenyl-
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Dibenzo[b,f][1,4]diazocine, 8-methyl-6,11-diphenyl-
1,2-Benzenedicarbonyl dichloride, 4-bromo-
1,2-Benzenedicarbonyl dichloride, 4-bromo-
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1,2-Benzenedicarbonyl dichloride, 4-bromo-
1,2-Benzenedicarbonyl dichloride, 4-chloro-
1,2-Benzenedicarbonyl dichloride, 4-chloro-
CAS:62366-66-9
1,2-Benzenedicarbonyl dichloride, 4-chloro-
DIBENZO[B,F][1,4]DIAZOCINE, 2-CHLORO-6,11-DIPHENYL-
DIBENZO[B,F][1,4]DIAZOCINE, 2-CHLORO-6,11-DIPHENYL-
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DIBENZO[B,F][1,4]DIAZOCINE, 2-CHLORO-6,11-DIPHENYL-