[1,1'-Biphenyl]-3,3'-dicarbonitrile

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BASIC PARAMETERS Find an error

CAS: 36852-02-5
MF: C14H8N2
MW: 204.22672
Synonyms: [1,1'-Biphenyl]-3,3'-dicarbonitrile

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Yoshito Kishi

Harvard University
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Co-reporter: Jianbiao Peng, Xiang Liu, Yoshito Kishi
pp: 2172-2175
Publication Date(Web):27 April 2011
DOI: 10.1016/j.tetlet.2010.11.124
A new catalytic system (cat. (H)2Phen(Me)2·NiCl2 or (MeO)2Dipyr(H)2·NiCl2, cat. Zr(cp)2Cl2, 2 equiv Mn, and 2 equiv LiCl) has been developed to facilitate the homocoupling of a wide range of aryl, alkenyl, and alkynyl halides.Image for unlabelled figure

George W. Kabalka

The University of Tennessee
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Co-reporter: Bryan Musolino, Michael Quinn, Kelly Hall, Vitali Coltuclu, George W. Kabalka
pp: 4080-4082
Publication Date(Web):31 July 2013
DOI: 10.1016/j.tetlet.2013.05.102
Using Dowex polymer supported aryltrifluoroborates, we are able to achieve homocoupling for a variety of compounds. The reactions were completed in 6 h, while producing high yields of the desired products. The reaction proceeds under mild conditions, using ultrasound as the energy source, copper acetate as the metal co-reactant, and aqueous ethanol as solvent.Image for unlabelled figure

Zhengjiang Fu

Nanchang University
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Hu Cai

Nanchang University
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