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CAS: 1221790-61-9
MF: C31H9BN5F2
MW: 500.24446
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Engin U. Akkaya

Bilkent University
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Modular logic gates: cascading independent logic gates via metal ion signals
Co-reporter: Esra Tanriverdi Ecik, Ahmet Atilgan, Ruslan Guliyev, T. Bilal Uyar, Aysegul Gumus and Engin U. Akkaya  
pp: 67-70
Publication Date(Web):30 Sep 2013
DOI: 10.1039/C3DT52375F
Systematic cascading of molecular logic gates is an important issue to be addressed for advancing research in this field. We have demonstrated that photochemically triggered metal ion signals can be utilized towards that goal. Thus, independent logic gates were shown to work together while keeping their identity in more complex logic designs. Communication through the intermediacy of ion signals is clearly inspired from biological processes modulated by such signals, and implemented here with ion responsive molecules.
Near-IR-Triggered, Remote-Controlled Release of Metal Ions: A Novel Strategy for Caged Ions
Co-reporter: Ahmet Atilgan;Dr. Esra TanriverdiEçik;Dr. Ruslan Guliyev;T. Bilal Uyar;Dr. Sundus Erbas-Cakmak;Dr. Engin U. Akkaya
pp: 10678-10681
Publication Date(Web):
DOI: 10.1002/anie.201405462

Abstract

A ligand incorporating a dithioethenyl moiety is cleaved into fragments which have a lower metal-ion affinity upon irradiation with low-energy red/near-IR light. The cleavage is a result of singlet oxygen generation which occurs on excitation of the photosensitizer modules. The method has many tunable factors that could make it a satisfactory caging strategy for metal ions.

Modular logic gates: cascading independent logic gates via metal ion signals
Co-reporter: Esra Tanriverdi Ecik, Ahmet Atilgan, Ruslan Guliyev, T. Bilal Uyar, Aysegul Gumus and Engin U. Akkaya
pp: NaN70-70
Publication Date(Web):2013/09/30
DOI: 10.1039/C3DT52375F
Systematic cascading of molecular logic gates is an important issue to be addressed for advancing research in this field. We have demonstrated that photochemically triggered metal ion signals can be utilized towards that goal. Thus, independent logic gates were shown to work together while keeping their identity in more complex logic designs. Communication through the intermediacy of ion signals is clearly inspired from biological processes modulated by such signals, and implemented here with ion responsive molecules.