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XiaoHui Fan

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Name: 樊晓辉; XiaoHui Fan
Organization: Lanzhou Jiaotong University
Department: School of Chemical and Biological Engineering
Title: Professor
Assembly of homoallylamine derivatives through iron-catalyzed three-component sulfonamidoallylation reaction
Co-reporter:Xiaohui Fan;Hong-Bo Zhu;Hao Lv;Kun Guo;Yong-Hong Guan;Xiao-Meng Cui;Bin An;Yan-Ling Pu
Applied Organometallic Chemistry 2015 Volume 29( Issue 9) pp:588-592
Publication Date(Web):
DOI:10.1002/aoc.3334

An efficient FeCl3-catalyzed three-component reaction between aldehydes, sulfonamides and allylsilanes has been achieved, which provides a convenient, atom-economic and green way to construct homoallylamine derivatives. In addition, this reaction exhibits excellent syn stereoselectivity with γ-substituted allylsilanes.

Assembly of indenamine derivatives through in situ formed N-sulfonyliminium ion initiated cyclization
Co-reporter:Xiaohui Fan, Hao Lv, Yong-Hong Guan, Hong-Bo Zhu, Xiao-Meng Cui and Kun Guo  
Chemical Communications 2014 vol. 50(Issue 31) pp:4119-4122
Publication Date(Web):26 Feb 2014
DOI:10.1039/C4CC00310A
An expedient route to structurally diverse indenamine derivatives through condensation of the readily accessible substituted cinnamylaldehydes and sulfonylamines under the catalysis of FeCl3 has been developed, featuring high efficiency in the generation of two bonds and one ring in a single-step and water as the only by-product.
Iron-Catalyzed -Activated CO Ether Bond Cleavage with CC and CH Bond Formation
Co-reporter:Xiaohui Fan;Xiao-Meng Cui;Yong-Hong Guan;Lin-An Fu;Hao Lv;Kun Guo;Hong-Bo Zhu
European Journal of Organic Chemistry 2014 Volume 2014( Issue 3) pp:498-501
Publication Date(Web):
DOI:10.1002/ejoc.201301372

Abstract

A novel and efficient allylic alkylation reaction between π-activated ethers and allylsilane was realized under mild conditions through iron(III)-catalyzed C–O ether bond cleavage. The present protocol provides an attractive approach for the construction of sp3–sp3 C–C bonds and can be potentially applied for the selective reduction of benzyl and allyl ethers to their corresponding hydrocarbon compounds by using triethylsilane as a hydride-transfer reagent.

A mild and efficient method for bromination of alcohols using α,α-dibromo-β-dicarbonyl compounds as halogen sources
Co-reporter:Xiao-Meng Cui, Yong-Hong Guan, Na Li, Hao Lv, Lin-An Fu, Kun Guo, Xiaohui Fan
Tetrahedron Letters 2014 Volume 55(Issue 1) pp:90-93
Publication Date(Web):1 January 2014
DOI:10.1016/j.tetlet.2013.10.120
Exploration of α,α-dibromo-β-dicarbonyl compounds as novel bromine agents for the conversion of alcohols to alkyl bromides under neutral conditions has been achieved. This method can be used for acid-sensitive substrates and allows the bromination of various primary and secondary alcohols to proceed at room temperature within a very short period of time.Exploration of α,α-dibromo-β-dicarbonyl compounds as novel bromine agents for the conversion of alcohols to alkyl bromides under neutral conditions has been achieved. This method can be used for acid-sensitive substrates and allows the bromination of various primary and secondary alcohols to proceed at room temperature within a very short period of time.
Efficient assembly of α-aryl and α-vinyl nitriles via iron-catalyzed ether bond activation
Co-reporter:Xiaohui Fan, Kun Guo, Yong-Hong Guan, Lin-An Fu, Xiao-Meng Cui, Hao Lv, Hong-Bo Zhu
Tetrahedron Letters 2014 Volume 55(Issue 5) pp:1068-1071
Publication Date(Web):29 January 2014
DOI:10.1016/j.tetlet.2013.12.083
A novel and practical method for the synthesis of diverse α-aryl and α-vinyl nitriles was developed via an iron-catalyzed sp3 C–O ether bond cleavage with C–C bond formation in the reaction of π-activated ethers with TMSCN.Direct cyanation of π-activated ethers to synthesis of α-aryl and α-vinyl nitriles via iron-catalyzed sp3 C–O ether bond cleavage was developed.
A mild CuI-catalyzed Glaser-type homo-coupling reaction using α,α-dibromo-β-dicarbonyl compounds as oxidants
Co-reporter:Xiaohui Fan, Na Li, Tong Shen, Xiao-Meng Cui, Hao Lv, Hong-Bo Zhu, Yong-Hong Guan
Tetrahedron 2014 70(2) pp: 256-261
Publication Date(Web):
DOI:10.1016/j.tet.2013.11.076
Iron-catalyzed N-alkylation using π-activated ethers as electrophiles
Co-reporter:Xiaohui Fan, Lin-An Fu, Na Li, Hao Lv, Xiao-Meng Cui and Yuan Qi  
Organic & Biomolecular Chemistry 2013 vol. 11(Issue 13) pp:2147-2153
Publication Date(Web):17 Jan 2013
DOI:10.1039/C3OB27128E
A new method for the synthesis of diverse N-alkylation compounds was developed via an iron-catalyzed etheric Csp3–O cleavage with the C–N bond formation in the reaction of π-activated ethers with various nitrogen-based nucleophiles. In addition, the mechanism of this reaction was investigated.
Assembly of indenamine derivatives through in situ formed N-sulfonyliminium ion initiated cyclization
Co-reporter:Xiaohui Fan, Hao Lv, Yong-Hong Guan, Hong-Bo Zhu, Xiao-Meng Cui and Kun Guo
Chemical Communications 2014 - vol. 50(Issue 31) pp:NaN4122-4122
Publication Date(Web):2014/02/26
DOI:10.1039/C4CC00310A
An expedient route to structurally diverse indenamine derivatives through condensation of the readily accessible substituted cinnamylaldehydes and sulfonylamines under the catalysis of FeCl3 has been developed, featuring high efficiency in the generation of two bonds and one ring in a single-step and water as the only by-product.
Iron-catalyzed N-alkylation using π-activated ethers as electrophiles
Co-reporter:Xiaohui Fan, Lin-An Fu, Na Li, Hao Lv, Xiao-Meng Cui and Yuan Qi
Organic & Biomolecular Chemistry 2013 - vol. 11(Issue 13) pp:NaN2153-2153
Publication Date(Web):2013/01/17
DOI:10.1039/C3OB27128E
A new method for the synthesis of diverse N-alkylation compounds was developed via an iron-catalyzed etheric Csp3–O cleavage with the C–N bond formation in the reaction of π-activated ethers with various nitrogen-based nucleophiles. In addition, the mechanism of this reaction was investigated.
CAS:1428319-09-8
CAS:957763-32-5
CAS:957763-30-3
2-Pentenal, 2-methyl-3-phenyl-, (2E)-
2-Pentenal, 2-methyl-3-phenyl-, (2E)-
CAS:864249-52-5
2-Pentenal, 2-methyl-3-phenyl-, (2E)-
Naphthalene, 1,2,3,4-tetrahydro-1-(2-propynyloxy)-
Naphthalene, 1,2,3,4-tetrahydro-1-(2-propynyloxy)-
CAS:757217-12-2
Naphthalene, 1,2,3,4-tetrahydro-1-(2-propynyloxy)-
Benzene, [(1E,3E)-6-bromo-1,3-hexadienyl]-
Benzene, [(1E,3E)-6-bromo-1,3-hexadienyl]-
CAS:627048-24-2
Benzene, [(1E,3E)-6-bromo-1,3-hexadienyl]-
Benzene, 1,1'-[2,4-hexadiyne-1,6-diylbis(oxy-3-butenylidene)]bis-
Benzene, 1,1'-[2,4-hexadiyne-1,6-diylbis(oxy-3-butenylidene)]bis-
CAS:609768-40-3
Benzene, 1,1'-[2,4-hexadiyne-1,6-diylbis(oxy-3-butenylidene)]bis-
Benzenemethanol, 2,4-dichloro-a-2-propenyl-
Benzenemethanol, 2,4-dichloro-a-2-propenyl-
CAS:301648-02-2
Benzenemethanol, 2,4-dichloro-a-2-propenyl-
Benzenesulfonamide, N-[1-(1,3-benzodioxol-5-yl)-3-butenyl]-4-methyl-
Benzenesulfonamide, N-[1-(1,3-benzodioxol-5-yl)-3-butenyl]-4-methyl-
CAS:243671-19-4
Benzenesulfonamide, N-[1-(1,3-benzodioxol-5-yl)-3-butenyl]-4-methyl-
CAS:243671-18-3