Atsushi Minami

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Organization: Hokkaido University

Department: Biotechnology Research Center

Title:

Chemicals
References

Identification and functional analysis of brassicicene C biosynthetic gene cluster in Alternaria brassicicola

Co-reporter:Atsushi Minami, Naoto Tajima, Yusuke Higuchi, Tomonobu Toyomasu, Takeshi Sassa, Nobuo Kato, Tohru Dairi

Bioorganic & Medicinal Chemistry Letters 2009 Volume 19(Issue 3) pp:870-874

Publication Date(Web):1 February 2009

DOI:10.1016/j.bmcl.2008.11.108

The biosynthetic gene cluster of brassicicene C was identified in Alternaria brassicicola strain ATCC 96836 from genome database search. In vivo and in vitro study clearly revealed the function of Orf8 and Orf6 as a fusicoccadiene synthase and methyltransferase, respectively. The understanding toward the biosynthetic pathway promises construction of this type of diterpene compounds with genetic engineering.The biosynthetic gene cluster of brassicicene C was identified in Alternaria brassicicola strain ATCC 96836 from genome database search.

CAS:1426414-26-7

N/A

CAS:1403768-99-9

CAS:1372857-65-2

CAS:1119804-71-5

methyl phomopsenonate

Benzenemethanol, 2,4-dimethoxy-3-methyl-5-(phenylmethoxy)-

CAS:866110-58-9

Benzenemethanol, 2,4-dimethoxy-3-methyl-5-(phenylmethoxy)-

Benzene, 5-(bromomethyl)-2-methoxy-1-methyl-3-(phenylmethoxy)-

CAS:575444-14-3

Benzene, 5-(bromomethyl)-2-methoxy-1-methyl-3-(phenylmethoxy)-

BENZENEMETHANOL, 4-METHOXY-3-METHYL-5-(PHENYLMETHOXY)-

CAS:575444-13-2

BENZENEMETHANOL, 4-METHOXY-3-METHYL-5-(PHENYLMETHOXY)-

Benzaldehyde, 4-methoxy-3-methyl-5-(phenylmethoxy)-

CAS:575444-12-1

Benzaldehyde, 4-methoxy-3-methyl-5-(phenylmethoxy)-

CAS:497162-51-3

CAS:475678-93-4

(3S,3aS,6S,6aR,7aS,10R,10aS,11aR,11bR,12aS)-11a-hydroxy-3,6,7a,11b-tetramethyl-10-(propan-2-yl)tetradecahydro-1H-cyclopenta[1,8]indeno[5',6':3,4]cycloocta[1,2-b]oxiren-9(10H)-one

CAS:199468-54-7

(3S,3aS,6S,6aR,7aS,10R,10aS,11aR,11bR,12aS)-11a-hydroxy-3,6,7a,11b-tetramethyl-10-(propan-2-yl)tetradecahydro-1H-cyclopenta[1,8]indeno[5',6':3,4]cycloocta[1,2-b]oxiren-9(10H)-one

(-)-2-[14-[4(E)-Hexenoyl]-18-[6(E)-octenyl]-3,7,9-trioxo-2,8,15-trioxapentacyclo[10.3.3.0(1,11).0(4,16).0(6,10)]octadeca-6(10),16-dien-4-yl]acetic acid

CAS:186700-09-4

(-)-2-[14-[4(E)-Hexenoyl]-18-[6(E)-octenyl]-3,7,9-trioxo-2,8,15-trioxapentacyclo[10.3.3.0(1,11).0(4,16).0(6,10)]octadeca-6(10),16-dien-4-yl]acetic acid

Pentanamide,2-[(5-fluoro-2,4-dinitrophenyl)amino]-4-methyl-, (2S)-

CAS:178065-29-7

Pentanamide,2-[(5-fluoro-2,4-dinitrophenyl)amino]-4-methyl-, (2S)-

Glycine, (bR)-b,5-dihydroxy-2-[(R)-(2-hydroxyethyl)sulfinyl]-N-methyl-L-tyrosyl-L-valyl-3-hydroxy-L-isoleucyl-,cyclic (15®3)-ether (9CI)

CAS:158274-98-7

Glycine, (bR)-b,5-dihydroxy-2-[(R)-(2-hydroxyethyl)sulfinyl]-N-methyl-L-tyrosyl-L-valyl-3-hydroxy-L-isoleucyl-,cyclic (15®3)-ether (9CI)

(2S)-2-[(3aS,13S,16aR)-2,13-dihydroxy-3a,6,10,14-tetramethyl-3-oxo-3,3a,4,7,8,11,12,13,16,16a-decahydrocyclopenta[15]annulen-1-yl]propyl acetate

CAS:152469-17-5

(2S)-2-[(3aS,13S,16aR)-2,13-dihydroxy-3a,6,10,14-tetramethyl-3-oxo-3,3a,4,7,8,11,12,13,16,16a-decahydrocyclopenta[15]annulen-1-yl]propyl acetate

CAS:148717-76-4

PC-M4

CAS:148717-75-3

PC-M5

CAS:144446-23-1

beta-Aflatrem

CAS:135513-21-2

Variculanol

2(1H)-Pyridinone,5-(2,5-dihydroxy-7-oxabicyclo[4.1.0]hept-2-yl)-1,4-dihydroxy-3-[(1,2,4a,5,6,7,8,8a-octahydro-2-methyl-1-naphthalenyl)carbonyl]-(9CI)

CAS:134822-63-2

2(1H)-Pyridinone,5-(2,5-dihydroxy-7-oxabicyclo[4.1.0]hept-2-yl)-1,4-dihydroxy-3-[(1,2,4a,5,6,7,8,8a-octahydro-2-methyl-1-naphthalenyl)carbonyl]-(9CI)

CAS:133613-75-9

PC-M5'

CAS:133101-16-3

Variecolin

3a,11a-Methano-4H-indeno[5,6-e]azulen-9-ol,tetradecahydro-3,6,7a-trimethyl-12-methylene-10-(1-methylethyl)-,(3R,3aR,6R,6aS,7aR,9S,10S,10aR,11aR,11bS)-rel- (9CI)

CAS:127393-74-2

3a,11a-Methano-4H-indeno[5,6-e]azulen-9-ol,tetradecahydro-3,6,7a-trimethyl-12-methylene-10-(1-methylethyl)-,(3R,3aR,6R,6aS,7aR,9S,10S,10aR,11aR,11bS)-rel- (9CI)

Cyclopenta[4,5]cyclooct[1,2-f]indene-6-carboxaldehyde,1,2,3,3a,4,6a,7,7a,8,9,10,10a,11,11a-tetradecahydro-3,7a,12-trimethyl-10-(1-methylethyl)-2-(b-D-xylopyranosyloxy)-, (2S,3S,3aS,6aS,7aR,10S,10aS,11aS)-(9CI)

CAS:122535-46-0

Cyclopenta[4,5]cyclooct[1,2-f]indene-6-carboxaldehyde,1,2,3,3a,4,6a,7,7a,8,9,10,10a,11,11a-tetradecahydro-3,7a,12-trimethyl-10-(1-methylethyl)-2-(b-D-xylopyranosyloxy)-, (2S,3S,3aS,6aS,7aR,10S,10aS,11aS)-(9CI)

6H-Benzo[d]naphtho[1,2-b]pyran-6-one,1-hydroxy-10,12-dimethoxy-8-methyl-

CAS:115475-80-4

6H-Benzo[d]naphtho[1,2-b]pyran-6-one,1-hydroxy-10,12-dimethoxy-8-methyl-

CAS:113670-16-9

4-[(2-hydroxyethyl)amino]-6-[(1R,2S,4aR,8aR)-2-methyl-1,2,4a,5,6,7,8,8a-octahydronaphthalen-1-yl]-2-oxo-2H-pyran-3-carbaldehyde

CAS:88899-59-6

4-[(2-hydroxyethyl)amino]-6-[(1R,2S,4aR,8aR)-2-methyl-1,2,4a,5,6,7,8,8a-octahydronaphthalen-1-yl]-2-oxo-2H-pyran-3-carbaldehyde

1(2H)-Naphthalenone, octahydro-2,7-dihydroxy-4-[(2Z)-3-hydroxy-1-oxo-2-propen-1-yl]-2,4,5,7-tetramethyl-3-[(1R)-1-methylpropyl]-,

CAS:85269-25-6

1(2H)-Naphthalenone, octahydro-2,7-dihydroxy-4-[(2Z)-3-hydroxy-1-oxo-2-propen-1-yl]-2,4,5,7-tetramethyl-3-[(1R)-1-methylpropyl]-,

(2S,3R,4R,4aS,5R,7R,8aS)-3-[(2R)-butan-2-yl]-2,7-dihydroxy-4-(3-hydroxypropanoyl)-2,4,5,7-tetramethyloctahydronaphthalen-1(2H)-one

CAS:85269-23-4

(2S,3R,4R,4aS,5R,7R,8aS)-3-[(2R)-butan-2-yl]-2,7-dihydroxy-4-(3-hydroxypropanoyl)-2,4,5,7-tetramethyloctahydronaphthalen-1(2H)-one

CAS:80286-58-4

Artemisinic acid

CAS:79127-24-5

(+)-INDOLACTAM V

(2R,3S,3aR,4aS,4bS,6aR,7S,7dR,8S,9aR,14bS,14cR,16aS)-14b,14c,17,17-tetramethyl-2-(1-methylethenyl)-10-methylidene-3,3a,6,6a,7,8,9,9a,10,11,14,14b,14c,15,16,16a-hexadecahydro-2H,4bH-7,8-(epoxymethano)cyclobuta[5,6]benzo[1,2-e]oxireno[4',4a']chromeno[5',6':

CAS:78213-66-8

(2R,3S,3aR,4aS,4bS,6aR,7S,7dR,8S,9aR,14bS,14cR,16aS)-14b,14c,17,17-tetramethyl-2-(1-methylethenyl)-10-methylidene-3,3a,6,6a,7,8,9,9a,10,11,14,14b,14c,15,16,16a-hexadecahydro-2H,4bH-7,8-(epoxymethano)cyclobuta[5,6]benzo[1,2-e]oxireno[4',4a']chromeno[5',6':

7,8-(Epoxymethano)-2H,6H-cyclobuta[5,6]benz[1,2-e]oxireno[4',4'a]-1-benzopyrano[5',6':6,7]indeno[1,2-b]indole-3,4b(5H)-diol, 12-chloro-

CAS:78213-65-7

7,8-(Epoxymethano)-2H,6H-cyclobuta[5,6]benz[1,2-e]oxireno[4',4'a]-1-benzopyrano[5',6':6,7]indeno[1,2-b]indole-3,4b(5H)-diol, 12-chloro-

(2R,3R,4bS,6aR,7S,7dS,8S,9aS,14bS,14cR,16aS)-14b,14c,17,17-tetramethyl-2-(1-methylethenyl)-10-methylidene-2,3,5,6,6a,7,7d,8,9,9a,10,11,14,14b,14c,15,16,16a-octadecahydro-4bH-7,8-(epoxymethano)chromeno[5',6':6,7]indeno[1,2-b]cyclobuta[5,6]benzo[1,2-e]indol

CAS:78213-64-6

(2R,3R,4bS,6aR,7S,7dS,8S,9aS,14bS,14cR,16aS)-14b,14c,17,17-tetramethyl-2-(1-methylethenyl)-10-methylidene-2,3,5,6,6a,7,7d,8,9,9a,10,11,14,14b,14c,15,16,16a-octadecahydro-4bH-7,8-(epoxymethano)chromeno[5',6':6,7]indeno[1,2-b]cyclobuta[5,6]benzo[1,2-e]indol

CAS:68654-85-3

4-Pentynal, 5-(trimethylsilyl)-

5b-hydroxy-2,2,13b,13c-tetramethyl-2,3,5b,6,7,7a,8,13,13b,13c,14,15-dodecahydro-4H-3,15a-epoxy[1]benzoxepino[6',7':6,7]indeno[1,2-b]indol-4-one

CAS:63722-91-8

5b-hydroxy-2,2,13b,13c-tetramethyl-2,3,5b,6,7,7a,8,13,13b,13c,14,15-dodecahydro-4H-3,15a-epoxy[1]benzoxepino[6',7':6,7]indeno[1,2-b]indol-4-one

(R)-2-Methoxy-2-(naphthalen-1-yl)propanoic acid

CAS:63628-26-2

(R)-2-Methoxy-2-(naphthalen-1-yl)propanoic acid

CAS:59678-46-5

ENTEROCIN

CAS:42272-93-5

ETHYL 5-METHYL-4-HEXENOATE

CAS:40184-98-3

Retigeransaeure

CAS:38966-21-1

APHIDICOLIN

7,8-(Epoxymethano)-4bH-1-benzopyrano[5',6':6,7]indeno[1,2-b]cyclobuta[5,6]benz[1,2-e]indole-3,4b-diol,12-chloro-2,3,5,6,6a,7,7d,8,9,9a,10,11,14,14b,14c,15,16,16a-octadecahydro-14b,14c,17,17-tetramethyl-10-methylene-2-(1-methylethenyl)-,(2R,3R,4bR,6aR,7S,7dS,8S,9aS,14bS,14cR,16aS)- (9CI)

CAS:37318-84-6

7,8-(Epoxymethano)-4bH-1-benzopyrano[5',6':6,7]indeno[1,2-b]cyclobuta[5,6]benz[1,2-e]indole-3,4b-diol,12-chloro-2,3,5,6,6a,7,7d,8,9,9a,10,11,14,14b,14c,15,16,16a-octadecahydro-14b,14c,17,17-tetramethyl-10-methylene-2-(1-methylethenyl)-,(2R,3R,4bR,6aR,7S,7dS,8S,9aS,14bS,14cR,16aS)- (9CI)

CAS:37203-49-9

Penitrem

CAS:37187-49-8

Cytochalasin

CAS:34718-92-8

Uridine, 5'-amino-5'-deoxy-

CAS:34495-74-4

4-Hexenoic acid, ethyl ester, (4E)-

CAS:28370-56-1

Uridine,5'-deoxy-5'-oxo-

CAS:20098-89-9

Ophiobolin F

Dicyclopenta[a,d]cyclooctene-4-carboxaldehyde,7-[(1S)-1,5-dimethyl-4-hexen-1-yl]-1,2,3,3a,6,6a,7,8,9,9a,10,10a-dodecahydro-1-hydroxy-1,9a-dimethyl-3-oxo-,(1R,3aS,6aS,7R,9aR,10aS)-

CAS:19022-51-6

Dicyclopenta[a,d]cyclooctene-4-carboxaldehyde,7-[(1S)-1,5-dimethyl-4-hexen-1-yl]-1,2,3,3a,6,6a,7,8,9,9a,10,10a-dodecahydro-1-hydroxy-1,9a-dimethyl-3-oxo-,(1R,3aS,6aS,7R,9aR,10aS)-

7,8-(Epoxymethano)-2H,6H-cyclobuta[5,6]benz[1,2-e]oxireno[4',4'a]-1-benzopyrano[5',6':6,7]indeno[1,2-b]indole-3,4b,7d(5H,7H)-triol,12-chloro-3,3a,6a,8,9,9a,10,11,14,14b,14c,15,16,16a-tetradecahydro-14b,14c,17,17-tetramethyl-10-methylene-2-(1-methylethenyl)-,(2R,3S,3aR,4aS,4bS,6aR,7S,7dR,8R,9aR,14bS,14cR,16aS)-

CAS:12627-35-9

7,8-(Epoxymethano)-2H,6H-cyclobuta[5,6]benz[1,2-e]oxireno[4',4'a]-1-benzopyrano[5',6':6,7]indeno[1,2-b]indole-3,4b,7d(5H,7H)-triol,12-chloro-3,3a,6a,8,9,9a,10,11,14,14b,14c,15,16,16a-tetradecahydro-14b,14c,17,17-tetramethyl-10-methylene-2-(1-methylethenyl)-,(2R,3S,3aR,4aS,4bS,6aR,7S,7dR,8R,9aR,14bS,14cR,16aS)-

7,8-(Epoxymethano)-2H,6H-cyclobuta[5,6]benz[1,2-e]oxireno[4',4'a]-1-benzopyrano[5',6':6,7]indeno[1,2-b]indole-3,4b(5H)-diol,3,3a,6a,7,7d,8,9,9a,10,11,14,14b,14c,15,16,16a-hexadecahydro-14b,14c,17,17-tetramethyl-10-methylene-2-(1-methylethenyl)-,(2R,3S,3aR,4aS,4bS,6aR,7S,7dS,8S,9aS,14bR,14cR,16aS)- (9CI)

CAS:11076-67-8

7,8-(Epoxymethano)-2H,6H-cyclobuta[5,6]benz[1,2-e]oxireno[4',4'a]-1-benzopyrano[5',6':6,7]indeno[1,2-b]indole-3,4b(5H)-diol,3,3a,6a,7,7d,8,9,9a,10,11,14,14b,14c,15,16,16a-hexadecahydro-14b,14c,17,17-tetramethyl-10-methylene-2-(1-methylethenyl)-,(2R,3S,3aR,4aS,4bS,6aR,7S,7dS,8S,9aS,14bR,14cR,16aS)- (9CI)

CAS:7500-86-9

TRINITROBENZOYL CHLORIDE

CAS:4611-05-6

OPHIOBOLIN A

2,3-dihydroxy-3-(1H-indol-3-yl)propyl dihydrogen phosphate

CAS:4220-97-7

2,3-dihydroxy-3-(1H-indol-3-yl)propyl dihydrogen phosphate

CAS:1393-48-2

Thiostrepton

(1AR,4R,4AR,7S,7AS,7BR)-1,1,4,7-TETRAMETHYLDECAHYDRO-1H-CYCLOPROP<WBR />A[E]AZULENE-4,7-DIOL

CAS:763-10-0

(1AR,4R,4AR,7S,7AS,7BR)-1,1,4,7-TETRAMETHYLDECAHYDRO-1H-CYCLOPROPA[E]AZULENE-4,7-DIOL

CAS:524-14-1

S-(hydrogen malonyl)coenzyme A

(2E,6E)-3,7,11-TRIMETHYL-2,6,10-DODECATRIEN-1-YL TRIHYDROGEN DIPH<WBR />OSPHATE

CAS:372-97-4

(2E,6E)-3,7,11-TRIMETHYL-2,6,10-DODECATRIEN-1-YL TRIHYDROGEN DIPHOSPHATE

CAS:358-71-4

Isopentenyl pyrophosphate

(3AR,4R,5R,6AS)-4-FORMYL-2-OXOHEXAHYDRO-2H-CYCLOPENTA[B]FURAN-5-Y<WBR />L 4-BIPHENYLCARBOXYLATE

CAS:72-89-9

(3AR,4R,5R,6AS)-4-FORMYL-2-OXOHEXAHYDRO-2H-CYCLOPENTA[B]FURAN-5-YL 4-BIPHENYLCARBOXYLATE

Uridine,5'-deoxy-5,6-dihydro-5'-[[(2E,4E)-5-[(1R,1'R,1''R,1'''R,2S,2'R,2''R,2'''S)-2'''-[(1E)-2-[(1R,2R)-2-methylcyclopropyl]ethenyl][1,1':2',1'':2'',1'''-quatercyclopropan]-2-yl]-1-oxo-2,4-pentadien-1-yl]amino]-

CAS:120500-69-8

Uridine,5'-deoxy-5,6-dihydro-5'-[[(2E,4E)-5-[(1R,1'R,1''R,1'''R,2S,2'R,2''R,2'''S)-2'''-[(1E)-2-[(1R,2R)-2-methylcyclopropyl]ethenyl][1,1':2',1'':2'',1'''-quatercyclopropan]-2-yl]-1-oxo-2,4-pentadien-1-yl]amino]-

CAS:20108-30-9

fusicoccin

CAS:17090-79-8

Monensin

5b-hydroxy-2,2,13b,13c-tetramethyl-9-(2-methylbut-3-en-2-yl)-2,3,5b,6,7,7a,8,13,13b,13c,14,15-dodecahydro-4H-3,15a-epoxy[1]benzoxepino[6',7':6,7]indeno[1,2-b]indol-4-one

CAS:70553-75-2

5b-hydroxy-2,2,13b,13c-tetramethyl-9-(2-methylbut-3-en-2-yl)-2,3,5b,6,7,7a,8,13,13b,13c,14,15-dodecahydro-4H-3,15a-epoxy[1]benzoxepino[6',7':6,7]indeno[1,2-b]indol-4-one

2H-1-Benzopyrano[5',6':6,7]indeno[1,2-b]indole-2-methanol,3,4,4a,4b,5,6,6a,7,12,12b,12c,13,14,14a-tetradecahydro-a,a,4a,12b,12c-pentamethyl-,(2S,4aS,4bR,6aS,12bS,12cS,14aS)-

CAS:11024-56-9

2H-1-Benzopyrano[5',6':6,7]indeno[1,2-b]indole-2-methanol,3,4,4a,4b,5,6,6a,7,12,12b,12c,13,14,14a-tetradecahydro-a,a,4a,12b,12c-pentamethyl-,(2S,4aS,4bR,6aS,12bS,12cS,14aS)-

Diphosphoric acid,P-[(2E,6E,10E)-3,7,11,15-tetramethyl-2,6,10,14-hexadecatetraen-1-yl] ester

CAS:6699-20-3

Diphosphoric acid,P-[(2E,6E,10E)-3,7,11,15-tetramethyl-2,6,10,14-hexadecatetraen-1-yl] ester

3-METHYLBUT-2-ENYL PHOSPHONO HYDROGEN PHOSPHATE

CAS:358-72-5

3-METHYLBUT-2-ENYL PHOSPHONO HYDROGEN PHOSPHATE

2H-Pyrano[2'',3'':5',6']benz[1',2':6,7]indeno[1,2-b]indol-3(4bH)-one,5,6,6a,7,12,12b,12c,13,14,14a-decahydro-4b-hydroxy-2-(1-hydroxy-1-methylethyl)-12b,12c-dimethyl-,(2R,4bS,6aS,12bS,12cR,14aS)-

CAS:57186-25-1

2H-Pyrano[2'',3'':5',6']benz[1',2':6,7]indeno[1,2-b]indol-3(4bH)-one,5,6,6a,7,12,12b,12c,13,14,14a-decahydro-4b-hydroxy-2-(1-hydroxy-1-methylethyl)-12b,12c-dimethyl-,(2R,4bS,6aS,12bS,12cR,14aS)-