Co-reporter:Susan E. Henkelis, Laura J. McCormick, David B. Cordes, Alexandra M.Z. Slawin, Russell E. Morris
Inorganic Chemistry Communications 2016 Volume 65() pp:21-23
Publication Date(Web):March 2016
DOI:10.1016/j.inoche.2016.01.007
•The first example of a non-polymeric Mg-H2dhtp complex is reported.•Obtained by one-pot reflux at lower pH than leads to a known MOF, CPO-27-Mg•Hydrogen bonding interactions construct a complex 3D network.A mononuclear complex of composition Mg(H2dhtp)(H2O)5·H2O has been prepared and characterised crystallographically.A new mononuclear Mg-dhtp compound with ligand 2,5-dihydroxyterephathilic acid (dhtp) was prepared and its crystal structure was determined.