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Jian Cao

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Organization: Hangzhou Normal University
Department: Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education
Title:
Synthesis of 3-Alkyl- or 3-Allenyl-2-amidobenzofurans via Electrophilic Cyclization of o-Anisole-Substituted Ynamides with Carbocations
Co-reporter:Yulong Kong, Kezhi Jiang, Jian Cao, Lingzi Fu, Lian Yu, Guoqiao Lai, Yuming Cui, Ziqiang Hu, and Guanhai Wang
Organic Letters 2013 Volume 15(Issue 2) pp:422-425
Publication Date(Web):January 9, 2013
DOI:10.1021/ol303474a
A facile carbocation-induced electrophilic cyclization reaction has been developed for the synthesis of 3-alkyl- or 3-allenyl-2-amidobenzofurans from o-anisole-substituted ynamides and diarylmethanol or 1,1-diarylprop-2-yn-1-ol.
Synthesis of δ-Carbolines via a Pd-Catalyzed Sequential Reaction from 2-Iodoanilines and N-Tosyl-enynamines
Co-reporter:Jian Cao, Yongping Xu, Yulong Kong, Yuming Cui, Ziqiang Hu, Guanhai Wang, Yuan Deng, and Guoqiao Lai
Organic Letters 2012 Volume 14(Issue 1) pp:38-41
Publication Date(Web):November 30, 2011
DOI:10.1021/ol2027762
A facile Pd-catalyzed sequential reaction has been developed for the synthesis of δ-carbolines from 2-iodoanilines and N-tosyl-enynamines. This protocol involves Larock heteroannulation/elimination/electrocyclization/oxidative aromatization cascade sequences and allows access to multisubstituted δ-carbolines in moderate to good yields.
Synthesis of allenamides by Pd-catalyzed coupling of 3-alkoxycarbonyloxy ynamides or 1-alkoxycarbonyloxy allenamides with arylboronic acids
Co-reporter:Jian Cao, Yulong Kong, Yuan Deng, Guoqiao Lai, Yuming Cui, Ziqiang Hu and Guanhai Wang  
Organic & Biomolecular Chemistry 2012 vol. 10(Issue 48) pp:9556-9561
Publication Date(Web):17 Oct 2012
DOI:10.1039/C2OB26727F
An efficient palladium-catalyzed method is reported for the synthesis of multi-substituted allenamides by Suzuki–Miyaura cross-coupling reaction between easily prepared 3-alkoxycarbonyloxy ynamides or 1-alkoxycarbonyloxy allenamides and arylboronic acids.
Synthesis of allenamides by Pd-catalyzed coupling of 3-alkoxycarbonyloxy ynamides or 1-alkoxycarbonyloxy allenamides with arylboronic acids
Co-reporter:Jian Cao, Yulong Kong, Yuan Deng, Guoqiao Lai, Yuming Cui, Ziqiang Hu and Guanhai Wang
Organic & Biomolecular Chemistry 2012 - vol. 10(Issue 48) pp:NaN9561-9561
Publication Date(Web):2012/10/17
DOI:10.1039/C2OB26727F
An efficient palladium-catalyzed method is reported for the synthesis of multi-substituted allenamides by Suzuki–Miyaura cross-coupling reaction between easily prepared 3-alkoxycarbonyloxy ynamides or 1-alkoxycarbonyloxy allenamides and arylboronic acids.
METHANESULFONAMIDE, N-(PHENYLETHYNYL)-N-(PHENYLMETHYL)-
METHANESULFONAMIDE, N-(PHENYLETHYNYL)-N-(PHENYLMETHYL)-
CAS:683246-90-4
METHANESULFONAMIDE, N-(PHENYLETHYNYL)-N-(PHENYLMETHYL)-
CAS:609769-61-1
Benzonitrile, 4-[2,2':6',2''-terpyridin]-4'-yl-
Benzonitrile, 4-[2,2':6',2''-terpyridin]-4'-yl-
CAS:502622-86-8
Benzonitrile, 4-[2,2':6',2''-terpyridin]-4'-yl-
Silane, [3,3-diphenyl-3-[(trimethylsilyl)oxy]-1-propynyl]trimethyl-
Silane, [3,3-diphenyl-3-[(trimethylsilyl)oxy]-1-propynyl]trimethyl-
CAS:350693-36-6
Silane, [3,3-diphenyl-3-[(trimethylsilyl)oxy]-1-propynyl]trimethyl-
2,4,6-tris(2-pyridyl)pyridine
2,4,6-tris(2-pyridyl)pyridine
CAS:322637-99-0
2,4,6-tris(2-pyridyl)pyridine
2,2':6',2''-Terpyridine, 4'-(3-pyridinyl)-
2,2':6',2''-Terpyridine, 4'-(3-pyridinyl)-
CAS:311341-20-5
2,2':6',2''-Terpyridine, 4'-(3-pyridinyl)-
2,2':6',2''-Terpyridine, 4'-[1,1'-biphenyl]-4-yl-
2,2':6',2''-Terpyridine, 4'-[1,1'-biphenyl]-4-yl-
CAS:279674-33-8
2,2':6',2''-Terpyridine, 4'-[1,1'-biphenyl]-4-yl-
4-(4-fluorophenyl)-2,6-dipyridin-2-ylpyridine
4-(4-fluorophenyl)-2,6-dipyridin-2-ylpyridine
CAS:209901-86-0
4-(4-fluorophenyl)-2,6-dipyridin-2-ylpyridine
Benzenesulfonamide, N-ethynyl-4-methyl-N-(phenylmethyl)-
Benzenesulfonamide, N-ethynyl-4-methyl-N-(phenylmethyl)-
CAS:205885-39-8
Benzenesulfonamide, N-ethynyl-4-methyl-N-(phenylmethyl)-
CAS:138710-29-9