Co-reporter:Russell Cox
Natural Product Reports 2014 vol. 31(Issue 10) pp:1405-1424
Publication Date(Web):25 Jul 2014
DOI:10.1039/C4NP00059E
Covering: 1942–2014
Oxidative rearrangements are key reactions during the biosyntheses of many secondary metabolites in fungi. This review highlights the most important examples of these reactions and aims to draw together key mechanistic themes to allow a better understanding and future exploitation of this key class of fungal catalysts.
Co-reporter:Andrew M. Bailey, Russell J. Cox, Kate Harley, Colin M. Lazarus, Thomas J. Simpson and Elizabeth Skellam
Chemical Communications 2007 (Issue 39) pp:4053-4055
Publication Date(Web):25 Jul 2007
DOI:10.1039/B708614H
Isolation and sequencing of a PKS gene isolated from xenovulene-producing cultures of Acremonium strictum indicated the presence of NT-, KS-, AT-, PT-, C-MeT- and R-domains; heterologous expression in Aspergillus oryzae resulted in the production of 3-methylorcinaldehyde, demonstrating the role of the terminal reductase domain in product release.
Co-reporter:Russell J. Cox, Andrew Sutherland, John C. Vederas
Bioorganic & Medicinal Chemistry 2000 Volume 8(Issue 5) pp:843-871
Publication Date(Web):May 2000
DOI:10.1016/S0968-0896(00)00044-4
Co-reporter:Andrew M. Bailey, Russell J. Cox, Kate Harley, Colin M. Lazarus, Thomas J. Simpson and Elizabeth Skellam
Chemical Communications 2007(Issue 39) pp:NaN4055-4055
Publication Date(Web):2007/07/25
DOI:10.1039/B708614H
Isolation and sequencing of a PKS gene isolated from xenovulene-producing cultures of Acremonium strictum indicated the presence of NT-, KS-, AT-, PT-, C-MeT- and R-domains; heterologous expression in Aspergillus oryzae resulted in the production of 3-methylorcinaldehyde, demonstrating the role of the terminal reductase domain in product release.
![Cyclopropanecarboxylic acid, 1-[[(1,1-dimethylethoxy)carbonyl]amino]-2-phenyl-, (4-nitrophenyl)methyl ester, (1R,2S)-rel-](/data/chemimg/2079000/99200-88-1.png)
![Cyclopropanecarboxylic acid, 1-[[(1,1-dimethylethoxy)carbonyl]amino]-2-phenyl-, (4-nitrophenyl)methyl ester, (1R,2S)-rel-](/data/chemimg/2079000/99200-88-1_b.png)
![3',7-dihydroxy-6'-methyl-2,6,11-trioxo-2,3,3',3a,4',5',6,6',11,11b-decahydrospiro[benzo[g]furo[3,2-c]isochromene-5,2'-pyran]-4'-yl acetate](http://img.cochemist.com/ccimg/59600/59554-11-9.png)
![3',7-dihydroxy-6'-methyl-2,6,11-trioxo-2,3,3',3a,4',5',6,6',11,11b-decahydrospiro[benzo[g]furo[3,2-c]isochromene-5,2'-pyran]-4'-yl acetate](http://img.cochemist.com/ccimg/59600/59554-11-9_b.png)
![1H-Cyclonona[1,2-c:5,6-c']difuran-1,3,6,8(4H)-tetrone,10-ethyl-5,9,10,11-tetrahydro-4-propyl-, (4S,10R)-](http://img.cochemist.com/ccimg/800/743-51-1.png)
![1H-Cyclonona[1,2-c:5,6-c']difuran-1,3,6,8(4H)-tetrone,10-ethyl-5,9,10,11-tetrahydro-4-propyl-, (4S,10R)-](http://img.cochemist.com/ccimg/800/743-51-1_b.png)
![4H-1-Benzopyran-4-one,2,3-dihydro-2,7-dihydroxy-2-[(4-hydroxy-2-oxo-2H-pyran-6-yl)methyl]-5-methyl-](http://img.cochemist.com/ccimg/625200/625120-84-5.png)
![4H-1-Benzopyran-4-one,2,3-dihydro-2,7-dihydroxy-2-[(4-hydroxy-2-oxo-2H-pyran-6-yl)methyl]-5-methyl-](http://img.cochemist.com/ccimg/625200/625120-84-5_b.png)
![4H-1-Benzopyran-4-one,2,3-dihydro-2,7-dihydroxy-5-[(4-hydroxy-2-oxo-2H-pyran-6-yl)methyl]-2-methyl-](http://img.cochemist.com/ccimg/625200/625120-83-4.png)
![4H-1-Benzopyran-4-one,2,3-dihydro-2,7-dihydroxy-5-[(4-hydroxy-2-oxo-2H-pyran-6-yl)methyl]-2-methyl-](http://img.cochemist.com/ccimg/625200/625120-83-4_b.png)
![8-Oxa-2,6-diaza-7-phosphadecanoic acid,2-[(1,1-dimethylethoxy)carbonyl]-7-ethoxy-5-oxo-, 1,1-dimethylethylester, 7-oxide](http://img.cochemist.com/ccimg/494300/494226-81-2.png)
![8-Oxa-2,6-diaza-7-phosphadecanoic acid,2-[(1,1-dimethylethoxy)carbonyl]-7-ethoxy-5-oxo-, 1,1-dimethylethylester, 7-oxide](http://img.cochemist.com/ccimg/494300/494226-81-2_b.png)
![2,4-Cyclohexadien-1-one,3,6-dihydroxy-2,6-dimethyl-4-[(2E,4E)-1-oxo-2,4-hexadienyl]-, (6S)-](http://img.cochemist.com/ccimg/251100/251091-31-3.png)
![2,4-Cyclohexadien-1-one,3,6-dihydroxy-2,6-dimethyl-4-[(2E,4E)-1-oxo-2,4-hexadienyl]-, (6S)-](http://img.cochemist.com/ccimg/251100/251091-31-3_b.png)
![Benzenesulfonic acid, 4-methyl-, 2-[(4-methoxyphenyl)methylene]hydrazide, sodium salt (1:1)](/data/chemimg/1298500/65609-71-4.png)
![Benzenesulfonic acid, 4-methyl-, 2-[(4-methoxyphenyl)methylene]hydrazide, sodium salt (1:1)](/data/chemimg/1298500/65609-71-4_b.png)
![Iron, chloro[5,10,15,20-tetraphenyl-21H,23H-porphinato(2-)-κN21,κN22,κN23,κN24]-, (SP-5-12)-](/data/chemimg/1024600/16456-81-8.png)
![Iron, chloro[5,10,15,20-tetraphenyl-21H,23H-porphinato(2-)-κN21,κN22,κN23,κN24]-, (SP-5-12)-](/data/chemimg/1024600/16456-81-8_b.png)
![3-Heptenedioic acid, 6-hydroxy-2-[[(phenylmethoxy)carbonyl]amino]-,dimethyl ester, (2S)-](http://img.cochemist.com/ccimg/294900/294871-69-5.png)
![3-Heptenedioic acid, 6-hydroxy-2-[[(phenylmethoxy)carbonyl]amino]-,dimethyl ester, (2S)-](http://img.cochemist.com/ccimg/294900/294871-69-5_b.png)
![7-Isoquinolinol,1,2,3,4-tetrahydro-1-[2-(3-hydroxy-4,5-dimethoxyphenyl)ethyl]-6-methoxy-2-methyl-,(1S)-](http://img.cochemist.com/ccimg/23100/23068-65-7.png)
![7-Isoquinolinol,1,2,3,4-tetrahydro-1-[2-(3-hydroxy-4,5-dimethoxyphenyl)ethyl]-6-methoxy-2-methyl-,(1S)-](http://img.cochemist.com/ccimg/23100/23068-65-7_b.png)
![(3AR,4R,5R,6AS)-4-FORMYL-2-OXOHEXAHYDRO-2H-CYCLOPENTA[B]FURAN-5-Y<WBR />L 4-BIPHENYLCARBOXYLATE](http://img.cochemist.com/ccimg/100/72-89-9.png)
![(3AR,4R,5R,6AS)-4-FORMYL-2-OXOHEXAHYDRO-2H-CYCLOPENTA[B]FURAN-5-Y<WBR />L 4-BIPHENYLCARBOXYLATE](http://img.cochemist.com/ccimg/100/72-89-9_b.png)
![Iron,[cyclo[glycylglycylglycyl-N5-(acetyl-kO)-N5-(hydroxy-kO)-L-ornithyl-N5-(acetyl-kO)-N5-(hydroxy-kO)-L-ornithyl-N5-(acetyl-kO)-N5-(hydroxy-kO)-L-ornithyl]ato(3-)]-, (OC-6-64)-](http://img.cochemist.com/ccimg/15700/15630-64-5.png)
![Iron,[cyclo[glycylglycylglycyl-N5-(acetyl-kO)-N5-(hydroxy-kO)-L-ornithyl-N5-(acetyl-kO)-N5-(hydroxy-kO)-L-ornithyl-N5-(acetyl-kO)-N5-(hydroxy-kO)-L-ornithyl]ato(3-)]-, (OC-6-64)-](http://img.cochemist.com/ccimg/15700/15630-64-5_b.png)
![9-[(E)-3-METHYL-4-[3,4,5-TRIHYDROXY-5-[[3-(3-HYDROXYBUTAN-2-YL)OXIRAN-2-YL]METHYL]OXAN-2-YL]BUT-2-ENOYL]OXYNONANOIC ACID](http://img.cochemist.com/ccimg/41000/40980-51-6.png)
![9-[(E)-3-METHYL-4-[3,4,5-TRIHYDROXY-5-[[3-(3-HYDROXYBUTAN-2-YL)OXIRAN-2-YL]METHYL]OXAN-2-YL]BUT-2-ENOYL]OXYNONANOIC ACID](http://img.cochemist.com/ccimg/41000/40980-51-6_b.png)
![[8,8'-Bi-1H-naphtho[2,3-c]pyran]-3,3'-diaceticacid,3,3',4,4',5,5',10,10'-octahydro-6,6',9,9'-tetrahydroxy-1,1'-dimethyl-5,5',10,10'-tetraoxo-,(1R,1'R,3S,3'S)-](http://img.cochemist.com/ccimg/1400/1397-77-9.png)
![[8,8'-Bi-1H-naphtho[2,3-c]pyran]-3,3'-diaceticacid,3,3',4,4',5,5',10,10'-octahydro-6,6',9,9'-tetrahydroxy-1,1'-dimethyl-5,5',10,10'-tetraoxo-,(1R,1'R,3S,3'S)-](http://img.cochemist.com/ccimg/1400/1397-77-9_b.png)
![3-[(2E,4E)-4,6-DIMETHYLOCTA-2,4-DIENOYL]-1,4-DIHYDROXY-5-(4-HYDROXYPHENYL)PYRIDIN-2-ONE](http://img.cochemist.com/ccimg/53900/53823-15-7.png)
![3-[(2E,4E)-4,6-DIMETHYLOCTA-2,4-DIENOYL]-1,4-DIHYDROXY-5-(4-HYDROXYPHENYL)PYRIDIN-2-ONE](http://img.cochemist.com/ccimg/53900/53823-15-7_b.png)
![Acetamide,N-[(7S)-5,6,7,9-tetrahydro-10-hydroxy-1,2,3-trimethoxy-9-oxobenzo[a]heptalen-7-yl]-](http://img.cochemist.com/ccimg/500/477-27-0.png)
![Acetamide,N-[(7S)-5,6,7,9-tetrahydro-10-hydroxy-1,2,3-trimethoxy-9-oxobenzo[a]heptalen-7-yl]-](http://img.cochemist.com/ccimg/500/477-27-0_b.png)
![L-erythro-L-glycero-D-altro-7-Trideculo-7,4-furanosonicacid,2,7-anhydro-3,4-di-C-carboxy-8,9,10,12,13-pentadeoxy-10-methylene-12-(phenylmethyl)-,11-acetate 5-[(2E,4S,6S)-4,6-dimethyl-2-octenoate], (7S)-](http://img.cochemist.com/ccimg/142600/142561-96-4.png)
![L-erythro-L-glycero-D-altro-7-Trideculo-7,4-furanosonicacid,2,7-anhydro-3,4-di-C-carboxy-8,9,10,12,13-pentadeoxy-10-methylene-12-(phenylmethyl)-,11-acetate 5-[(2E,4S,6S)-4,6-dimethyl-2-octenoate], (7S)-](http://img.cochemist.com/ccimg/142600/142561-96-4_b.png)
![2-Oxazolidinone, 3-hydroxy-4-[(phosphonooxy)methyl]-, (4S)-](http://img.cochemist.com/ccimg/885800/885706-36-5.png)
![2-Oxazolidinone, 3-hydroxy-4-[(phosphonooxy)methyl]-, (4S)-](http://img.cochemist.com/ccimg/885800/885706-36-5_b.png)
![1,3-Propanediol, 2-[(phenylmethoxy)amino]-](http://img.cochemist.com/ccimg/885800/885706-32-1.png)
![1,3-Propanediol, 2-[(phenylmethoxy)amino]-](http://img.cochemist.com/ccimg/885800/885706-32-1_b.png)
![2-Oxazolidinone, 4-[(phosphonooxy)methyl]-, (4S)-](http://img.cochemist.com/ccimg/885800/885706-27-4.png)
![2-Oxazolidinone, 4-[(phosphonooxy)methyl]-, (4S)-](http://img.cochemist.com/ccimg/885800/885706-27-4_b.png)
![2-Oxazolidinone, 5-[(phosphonooxy)methyl]-, (5R)-](http://img.cochemist.com/ccimg/885800/885706-38-7.png)
![2-Oxazolidinone, 5-[(phosphonooxy)methyl]-, (5R)-](http://img.cochemist.com/ccimg/885800/885706-38-7_b.png)
![Phosphonic acid, [3-(acetylamino)propyl]-](http://img.cochemist.com/ccimg/885800/885706-25-2.png)
![Phosphonic acid, [3-(acetylamino)propyl]-](http://img.cochemist.com/ccimg/885800/885706-25-2_b.png)
![Butanoic acid, 4-oxo-4-[[(3S)-tetrahydro-2-oxo-3-furanyl]amino]-](http://img.cochemist.com/ccimg/382700/382602-03-1.png)
![Butanoic acid, 4-oxo-4-[[(3S)-tetrahydro-2-oxo-3-furanyl]amino]-](http://img.cochemist.com/ccimg/382700/382602-03-1_b.png)
![L-Ornithine, N2-acetyl-N5-[(phenylmethoxy)carbonyl]-](http://img.cochemist.com/ccimg/35600/35515-72-1.png)
![L-Ornithine, N2-acetyl-N5-[(phenylmethoxy)carbonyl]-](http://img.cochemist.com/ccimg/35600/35515-72-1_b.png)
![3-Butenoic acid, 2-[[(phenylmethoxy)carbonyl]amino]-, methyl ester](http://img.cochemist.com/ccimg/80700/80656-34-4.png)
![3-Butenoic acid, 2-[[(phenylmethoxy)carbonyl]amino]-, methyl ester](http://img.cochemist.com/ccimg/80700/80656-34-4_b.png)
![Propanoic acid, 3-[[2-(acetylamino)ethyl]thio]-3-oxo-](http://img.cochemist.com/ccimg/41000/40950-55-8.png)
![Propanoic acid, 3-[[2-(acetylamino)ethyl]thio]-3-oxo-](http://img.cochemist.com/ccimg/41000/40950-55-8_b.png)
![Homocysteine, N-[(phenylmethoxy)carbonyl]-, methyl ester](http://img.cochemist.com/ccimg/382700/382601-87-8.png)
![Homocysteine, N-[(phenylmethoxy)carbonyl]-, methyl ester](http://img.cochemist.com/ccimg/382700/382601-87-8_b.png)
![L-Homoserine, N,N-bis[(1,1-dimethylethoxy)carbonyl]-, methyl ester](http://img.cochemist.com/ccimg/224200/224192-24-9.png)
![L-Homoserine, N,N-bis[(1,1-dimethylethoxy)carbonyl]-, methyl ester](http://img.cochemist.com/ccimg/224200/224192-24-9_b.png)
![4-Pentenoic acid, 2-[(methoxycarbonyl)amino]-, methyl ester, (±)-](http://img.cochemist.com/ccimg/107000/106928-47-6.png)
![4-Pentenoic acid, 2-[(methoxycarbonyl)amino]-, methyl ester, (±)-](http://img.cochemist.com/ccimg/107000/106928-47-6_b.png)
![1H-Imidazole, 1-[(2-methyl-1,3-dioxolan-2-yl)acetyl]-](http://img.cochemist.com/ccimg/116200/116149-27-0.png)
![1H-Imidazole, 1-[(2-methyl-1,3-dioxolan-2-yl)acetyl]-](http://img.cochemist.com/ccimg/116200/116149-27-0_b.png)
![Homoserine, N-[(phenylmethoxy)carbonyl]-, methyl ester](http://img.cochemist.com/ccimg/112300/112229-39-7.png)
![Homoserine, N-[(phenylmethoxy)carbonyl]-, methyl ester](http://img.cochemist.com/ccimg/112300/112229-39-7_b.png)
![2-OXAZOLIDINONE, 3-HYDROXY-4-[(PHOSPHONOOXY)METHYL]-](http://img.cochemist.com/ccimg/885800/885706-35-4.png)
![2-OXAZOLIDINONE, 3-HYDROXY-4-[(PHOSPHONOOXY)METHYL]-](http://img.cochemist.com/ccimg/885800/885706-35-4_b.png)
![2-OXAZOLIDINONE, 5-[(PHOSPHONOOXY)METHYL]-, (5S)-](http://img.cochemist.com/ccimg/885800/885706-30-9.png)
![2-OXAZOLIDINONE, 5-[(PHOSPHONOOXY)METHYL]-, (5S)-](http://img.cochemist.com/ccimg/885800/885706-30-9_b.png)
![2-OXAZOLIDINONE, 4-[(PHOSPHONOOXY)METHYL]-, (4R)-](http://img.cochemist.com/ccimg/885800/885706-37-6.png)
![2-OXAZOLIDINONE, 4-[(PHOSPHONOOXY)METHYL]-, (4R)-](http://img.cochemist.com/ccimg/885800/885706-37-6_b.png)
![Heptanedioic acid, 2-[(3-carboxy-1-oxopropyl)amino]-6-oxo-, (2S)-](http://img.cochemist.com/ccimg/153500/153484-05-0.png)
![Heptanedioic acid, 2-[(3-carboxy-1-oxopropyl)amino]-6-oxo-, (2S)-](http://img.cochemist.com/ccimg/153500/153484-05-0_b.png)
![3-Pentyn-2-ol, 5-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-](http://img.cochemist.com/ccimg/215000/214978-04-8.png)
![3-Pentyn-2-ol, 5-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-](http://img.cochemist.com/ccimg/215000/214978-04-8_b.png)
![L-Phenylalanine, N-[(2,4-dimethoxyphenyl)methyl]-, methyl ester](http://img.cochemist.com/ccimg/213600/213547-32-1.png)
![L-Phenylalanine, N-[(2,4-dimethoxyphenyl)methyl]-, methyl ester](http://img.cochemist.com/ccimg/213600/213547-32-1_b.png)
![4-Pentenoic acid, 2-[acetyl(benzoyloxy)amino]-, methyl ester](http://img.cochemist.com/ccimg/746700/746656-75-7.png)
![4-Pentenoic acid, 2-[acetyl(benzoyloxy)amino]-, methyl ester](http://img.cochemist.com/ccimg/746700/746656-75-7_b.png)
![Acetic acid, [(benzoyloxy)imino]-, 1,1-dimethylethyl ester](http://img.cochemist.com/ccimg/746700/746656-72-4.png)
![Acetic acid, [(benzoyloxy)imino]-, 1,1-dimethylethyl ester](http://img.cochemist.com/ccimg/746700/746656-72-4_b.png)
![Acetic acid, [(phenylmethoxy)imino]-, (4-nitrophenyl)methyl ester](http://img.cochemist.com/ccimg/746700/746656-73-5.png)
![Acetic acid, [(phenylmethoxy)imino]-, (4-nitrophenyl)methyl ester](http://img.cochemist.com/ccimg/746700/746656-73-5_b.png)
![4-Pentenoic acid, 2-[acetyl(benzoyloxy)amino]-, 1,1-dimethylethyl ester](http://img.cochemist.com/ccimg/746700/746656-77-9.png)
![4-Pentenoic acid, 2-[acetyl(benzoyloxy)amino]-, 1,1-dimethylethyl ester](http://img.cochemist.com/ccimg/746700/746656-77-9_b.png)
![Butanoic acid, 3-[(benzoyloxy)imino]-, methyl ester](http://img.cochemist.com/ccimg/746700/746656-83-7.png)
![Butanoic acid, 3-[(benzoyloxy)imino]-, methyl ester](http://img.cochemist.com/ccimg/746700/746656-83-7_b.png)
![Propanoic acid, 2-[(benzoyloxy)imino]-, methyl ester](http://img.cochemist.com/ccimg/746700/746656-81-5.png)
![Propanoic acid, 2-[(benzoyloxy)imino]-, methyl ester](http://img.cochemist.com/ccimg/746700/746656-81-5_b.png)
![Acetic acid, [(benzoyloxy)imino]-, methyl ester](http://img.cochemist.com/ccimg/746700/746656-71-3.png)
![Acetic acid, [(benzoyloxy)imino]-, methyl ester](http://img.cochemist.com/ccimg/746700/746656-71-3_b.png)
![Acetic acid, [[(1-oxo-3-butenyl)oxy]imino]-, methyl ester](http://img.cochemist.com/ccimg/746700/746656-64-4.png)
![Acetic acid, [[(1-oxo-3-butenyl)oxy]imino]-, methyl ester](http://img.cochemist.com/ccimg/746700/746656-64-4_b.png)
![t-Butyl (2S)-2-[(Benzyloxycarbonylamino)]-4-hydroxybutyrate](http://img.cochemist.com/ccimg/78300/78266-81-6.png)
![t-Butyl (2S)-2-[(Benzyloxycarbonylamino)]-4-hydroxybutyrate](http://img.cochemist.com/ccimg/78300/78266-81-6_b.png)
![Di-tert-butyl (2S)-2-[N-(benzyloxycarbonyl)amino]-6-oxo-5-oxapimelate](http://img.cochemist.com/ccimg/382700/382602-02-0.png)
![Di-tert-butyl (2S)-2-[N-(benzyloxycarbonyl)amino]-6-oxo-5-oxapimelate](http://img.cochemist.com/ccimg/382700/382602-02-0_b.png)
![2-Propyn-1-one, 3-phenyl-1-[4-(phenylethynyl)phenyl]-](http://img.cochemist.com/ccimg/850000/849941-88-4.png)
![2-Propyn-1-one, 3-phenyl-1-[4-(phenylethynyl)phenyl]-](http://img.cochemist.com/ccimg/850000/849941-88-4_b.png)
![2-Propyn-1-one, 3-[(1,1-dimethylethyl)dimethylsilyl]-1-phenyl-](http://img.cochemist.com/ccimg/850000/849941-86-2.png)
![2-Propyn-1-one, 3-[(1,1-dimethylethyl)dimethylsilyl]-1-phenyl-](http://img.cochemist.com/ccimg/850000/849941-86-2_b.png)
![4-Pentenoic acid, 2-[acetyl(phenylmethoxy)amino]-, 1,1-dimethylethylester](http://img.cochemist.com/ccimg/746700/746656-76-8.png)
![4-Pentenoic acid, 2-[acetyl(phenylmethoxy)amino]-, 1,1-dimethylethylester](http://img.cochemist.com/ccimg/746700/746656-76-8_b.png)
![4-Pentenoic acid, 2-[(benzoyloxy)amino]-2-methyl-, methyl ester](http://img.cochemist.com/ccimg/746700/746656-85-9.png)
![4-Pentenoic acid, 2-[(benzoyloxy)amino]-2-methyl-, methyl ester](http://img.cochemist.com/ccimg/746700/746656-85-9_b.png)
![4-Pentenoic acid, 2-[acetyl(phenylmethoxy)amino]-, methyl ester](http://img.cochemist.com/ccimg/746700/746656-69-9.png)
![4-Pentenoic acid, 2-[acetyl(phenylmethoxy)amino]-, methyl ester](http://img.cochemist.com/ccimg/746700/746656-69-9_b.png)
![4-Pentenoic acid, 2-[acetyl(benzoyloxy)amino]-3-methyl-, methyl ester](http://img.cochemist.com/ccimg/746700/746656-88-2.png)
![4-Pentenoic acid, 2-[acetyl(benzoyloxy)amino]-3-methyl-, methyl ester](http://img.cochemist.com/ccimg/746700/746656-88-2_b.png)
![4-Pentenoic acid, 2-[acetyl(phenylmethoxy)amino]-,(4-nitrophenyl)methyl ester](http://img.cochemist.com/ccimg/746700/746656-78-0.png)
![4-Pentenoic acid, 2-[acetyl(phenylmethoxy)amino]-,(4-nitrophenyl)methyl ester](http://img.cochemist.com/ccimg/746700/746656-78-0_b.png)
![Acetic acid, [ethyl(1-methylethyl)amino]oxo-, methyl ester](http://img.cochemist.com/ccimg/850000/849941-92-0.png)
![Acetic acid, [ethyl(1-methylethyl)amino]oxo-, methyl ester](http://img.cochemist.com/ccimg/850000/849941-92-0_b.png)
![4-Pentenoic acid, 2-[(benzoyloxy)amino]-, methyl ester](http://img.cochemist.com/ccimg/746700/746656-89-3.png)
![4-Pentenoic acid, 2-[(benzoyloxy)amino]-, methyl ester](http://img.cochemist.com/ccimg/746700/746656-89-3_b.png)
![4-Pentenoic acid, 2-[acetyl[(1-oxo-3-butenyl)oxy]amino]-, methyl ester](http://img.cochemist.com/ccimg/746700/746656-70-2.png)
![4-Pentenoic acid, 2-[acetyl[(1-oxo-3-butenyl)oxy]amino]-, methyl ester](http://img.cochemist.com/ccimg/746700/746656-70-2_b.png)
![4-Pentenoic acid, 2-[[(1-oxo-3-butenyl)oxy]amino]-, methyl ester](http://img.cochemist.com/ccimg/746700/746656-65-5.png)
![4-Pentenoic acid, 2-[[(1-oxo-3-butenyl)oxy]amino]-, methyl ester](http://img.cochemist.com/ccimg/746700/746656-65-5_b.png)
![Butanoic acid, 3-[(phenylmethoxy)imino]-, methyl ester](http://img.cochemist.com/ccimg/746700/746656-82-6.png)
![Butanoic acid, 3-[(phenylmethoxy)imino]-, methyl ester](http://img.cochemist.com/ccimg/746700/746656-82-6_b.png)
![4-Pentenoic acid, 2-[acetyl(benzoyloxy)amino]-2-methyl-, methyl ester](http://img.cochemist.com/ccimg/746700/746656-84-8.png)
![4-Pentenoic acid, 2-[acetyl(benzoyloxy)amino]-2-methyl-, methyl ester](http://img.cochemist.com/ccimg/746700/746656-84-8_b.png)
![Acetic acid, [(benzoyloxy)imino]-, (4-nitrophenyl)methyl ester](http://img.cochemist.com/ccimg/746700/746656-74-6.png)
![Acetic acid, [(benzoyloxy)imino]-, (4-nitrophenyl)methyl ester](http://img.cochemist.com/ccimg/746700/746656-74-6_b.png)
![4-Pentenoic acid, 2-[(phenylmethoxy)amino]-, methyl ester](http://img.cochemist.com/ccimg/669100/669070-52-4.png)
![4-Pentenoic acid, 2-[(phenylmethoxy)amino]-, methyl ester](http://img.cochemist.com/ccimg/669100/669070-52-4_b.png)
![Propanoic acid, 2-[(phenylmethoxy)imino]-, methyl ester](http://img.cochemist.com/ccimg/353800/353796-63-1.png)
![Propanoic acid, 2-[(phenylmethoxy)imino]-, methyl ester](http://img.cochemist.com/ccimg/353800/353796-63-1_b.png)
![L-Aspartic acid, N,N-bis[(1,1-dimethylethoxy)carbonyl]-, dimethyl ester](http://img.cochemist.com/ccimg/219700/219617-08-0.png)
![L-Aspartic acid, N,N-bis[(1,1-dimethylethoxy)carbonyl]-, dimethyl ester](http://img.cochemist.com/ccimg/219700/219617-08-0_b.png)
![(2S,6S)-2-amino-6-[(3-carboxypropanoyl)amino]heptanedioic acid](http://img.cochemist.com/ccimg/26700/26605-36-7.png)
![(2S,6S)-2-amino-6-[(3-carboxypropanoyl)amino]heptanedioic acid](http://img.cochemist.com/ccimg/26700/26605-36-7_b.png)
![2-Propenoic acid, 2-[bis[(1,1-dimethylethoxy)carbonyl]amino]-, methylester](http://img.cochemist.com/ccimg/201400/201338-62-7.png)
![2-Propenoic acid, 2-[bis[(1,1-dimethylethoxy)carbonyl]amino]-, methylester](http://img.cochemist.com/ccimg/201400/201338-62-7_b.png)
![N-(5-oxo-4,5-dihydro[1,2]dithiolo[4,3-b]pyrrol-6-yl)octanamide](http://img.cochemist.com/ccimg/92700/92680-91-6.png)
![N-(5-oxo-4,5-dihydro[1,2]dithiolo[4,3-b]pyrrol-6-yl)octanamide](http://img.cochemist.com/ccimg/92700/92680-91-6_b.png)
![Phosphonic acid,[3-(acetylamino)propyl]-, diethyl ester (9CI)](http://img.cochemist.com/ccimg/54100/54008-28-5.png)
![Phosphonic acid,[3-(acetylamino)propyl]-, diethyl ester (9CI)](http://img.cochemist.com/ccimg/54100/54008-28-5_b.png)
![2-Butyn-1-one, 4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-1-phenyl-](http://img.cochemist.com/ccimg/81600/81535-84-4.png)
![2-Butyn-1-one, 4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-1-phenyl-](http://img.cochemist.com/ccimg/81600/81535-84-4_b.png)
![Acetic acid, [(phenylmethoxy)imino]-, methyl ester](http://img.cochemist.com/ccimg/120200/120104-68-9.png)
![Acetic acid, [(phenylmethoxy)imino]-, methyl ester](http://img.cochemist.com/ccimg/120200/120104-68-9_b.png)
![1,2-Dithiolo[4,3-b]pyrrol-5(4H)-one,6-amino-4-methyl-](http://img.cochemist.com/ccimg/700/642-77-3.png)
![1,2-Dithiolo[4,3-b]pyrrol-5(4H)-one,6-amino-4-methyl-](http://img.cochemist.com/ccimg/700/642-77-3_b.png)
![Phosphonic acid,P-[difluoro(trimethylsilyl)methyl]-, diethyl ester](http://img.cochemist.com/ccimg/80100/80077-72-1.png)
![Phosphonic acid,P-[difluoro(trimethylsilyl)methyl]-, diethyl ester](http://img.cochemist.com/ccimg/80100/80077-72-1_b.png)
![Butanethioic acid,3-oxo-, S-[2-(acetylamino)ethyl] ester](http://img.cochemist.com/ccimg/23300/23255-41-6.png)
![Butanethioic acid,3-oxo-, S-[2-(acetylamino)ethyl] ester](http://img.cochemist.com/ccimg/23300/23255-41-6_b.png)
![TERT-BUTYL-DIMETHYL-[1-[(2-METHYLPROPAN-2-YL)OXY]ETHENOXY]SILANE](http://img.cochemist.com/ccimg/74800/74786-02-0.png)
![TERT-BUTYL-DIMETHYL-[1-[(2-METHYLPROPAN-2-YL)OXY]ETHENOXY]SILANE](http://img.cochemist.com/ccimg/74800/74786-02-0_b.png)
![Benzaldehyde, 3-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-](http://img.cochemist.com/ccimg/96100/96013-95-5.png)
![Benzaldehyde, 3-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-](http://img.cochemist.com/ccimg/96100/96013-95-5_b.png)
![Serine, N-[(1,1-dimethylethoxy)carbonyl]-, (4-nitrophenyl)methyl ester](http://img.cochemist.com/ccimg/123400/123311-11-5.png)
![Serine, N-[(1,1-dimethylethoxy)carbonyl]-, (4-nitrophenyl)methyl ester](http://img.cochemist.com/ccimg/123400/123311-11-5_b.png)
![Acetic acid, [(phenylmethoxy)imino]-, 1,1-dimethylethyl ester](http://img.cochemist.com/ccimg/120200/120104-69-0.png)
![Acetic acid, [(phenylmethoxy)imino]-, 1,1-dimethylethyl ester](http://img.cochemist.com/ccimg/120200/120104-69-0_b.png)
![6,8-dihydroxycyclohepta[c]furan-1,3,5-trione](http://img.cochemist.com/ccimg/700/606-39-3.png)
![6,8-dihydroxycyclohepta[c]furan-1,3,5-trione](http://img.cochemist.com/ccimg/700/606-39-3_b.png)
![[4-(2-{[(2R)-2-HYDROXY-2-PHENYLETHYL]AMINO}ETHOXY)PHENYL]ACETIC A<WBR />CID](http://img.cochemist.com/ccimg/72000/71980-98-8.png)
![[4-(2-{[(2R)-2-HYDROXY-2-PHENYLETHYL]AMINO}ETHOXY)PHENYL]ACETIC A<WBR />CID](http://img.cochemist.com/ccimg/72000/71980-98-8_b.png)
![Silane, [[(1S,2R)-1,2-dimethyl-3-buten-1-yl]oxy]triethyl-](http://img.cochemist.com/ccimg/919300/919297-94-2.png)
![Silane, [[(1S,2R)-1,2-dimethyl-3-buten-1-yl]oxy]triethyl-](http://img.cochemist.com/ccimg/919300/919297-94-2_b.png)
![SODIUM;N-[(E)-BENZYLIDENEAMINO]-4-METHYLBENZENESULFONAMIDE](http://img.cochemist.com/ccimg/40200/40154-38-9.png)
![SODIUM;N-[(E)-BENZYLIDENEAMINO]-4-METHYLBENZENESULFONAMIDE](http://img.cochemist.com/ccimg/40200/40154-38-9_b.png)
