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CAS: 163359-60-2
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JianHui Hou

Institute of Chemistry, Chinese Academy of Sciences
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Co-reporter: Qi Xu, Fuzhi Wang, Deping Qian, Zhan’ao Tan, Liangjie Li, Shusheng Li, Xiaohe Tu, Gang Sun, Xuliang Hou, Jianhui Hou, and Yongfang Li
pp: 6591
Publication Date(Web):June 19, 2013
DOI: 10.1021/am401263m
An integrated device architecture was constructed via vertical combination of planar and bulk heterojunctions by solution processing, where a cross-linked D-A copolymer (PBDTTT-Br25) was inserted between a PEDOT:PSS layer and the blended photoactive layer. PBDTTT-Br25 can readily undergo photo crosslinking to form an insoluble robust film via ultraviolet irradiation after solution–deposition, which enables the subsequent solution processing of a photoactive layer on the robust surface. The insertion of a pure PBDTTT-Br25 layer to build an integrated heterojunction could provide an additional donor/acceptor interface, which enables hole transport to the anode without interruption, thereby reducing the charge carrier recombination probability. The power conversion efficiency (PCE) of the polymer solar cell (PSC) with the integrated architecture reaches 5.24% under an AM1.5G illumination of 100 mW/cm2, which is increased by 65%, in comparison with that of the reference single heterojunction device (3.17%), under the same experimental conditions.Keywords: bulk heterojunction solar cells; D-A copolymer; integrated architecture; photo-cross-linkable conjugated polymers; planar solar cells;

Daoben Zhu

Institute of Chemistry, Chinese Academy of Sciences
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Jizheng Wang

Institute of Chemistry, Chinese Academy of Sciences
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WenQiang Qiao

Changchun Institute of Applied Chemistry, Chinese Academy of Sciences
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Jiangbin Xia

Wuhan University
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Song-Sheng Qu

Wuhan University
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ZhiGang Shuai

Tsinghua University
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Dong Wang

Tsinghua University
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Xiaofeng Lu

Jilin University
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Ce Wang

Jilin University
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