Structuredsearch

Anthra[2,1,9-def:6,5,10-d'e'f']diisoquinoline-1,3,8,10(2H,9H)-tetrone, 5-bromo-2,9-bis(2-ethylhexyl)-12-methoxy-

Collect

BASIC PARAMETERS Find an error

CAS: 1356240-60-2
MF: C41H43N2O5Br
MW: 723.69452
Synonyms: Anthra[2,1,9-def:6,5,10-d'e'f']diisoquinoline-1,3,8,10(2H,9H)-tetrone, 5-bromo-2,9-bis(2-ethylhexyl)-12-methoxy-
Supply Source
I can Supply this

REPORT BY

Sheng-Gui He

Institute of Chemistry, Chinese Academy of Sciences
follow

Chuanlang Zhan

Institute of Chemistry, Chinese Academy of Sciences
follow
Facile synthesis of 1-bromo-7-alkoxyl perylene diimide dyes: toward unsymmetrical functionalizations at the 1,7-positions
Co-reporter: Xin Zhang, Shufeng Pang, Zhigang Zhang, Xunlei Ding, Shanlin Zhang, Shenggui He, Chuanlang Zhan
pp: 1094-1097
Publication Date(Web):29 February 2012
DOI: 10.1016/j.tetlet.2011.12.080
In this Letter, we report a facile approach to synthesize unsymmetrical 1-bromo-7-alkoxyl perylene diimides by the nucleophilic substitution of one of the two 1,7-dibromo units with an alkyl alcohol using K2CO3 as the base. A further replacement of another bromo, for example, by using 4-hydroxylpyridine resulted in unsymmetrical functionalizations at the 1,7-positions. The optical properties of the unsymmetrical PDI derivative were reported and compared with those of the symmetrical derivative.In this Letter, we report a facile approach to synthesize unsymmetrical 1-bromo-7-alkoxyl perylene diimides by the nucleophilic substitution of one of the two 1,7-dibromo units with an alkyl alcohol using K2CO3 as the base. A further replacement of another bromo, for example, by using 4-hydroxylpyridine resulted in unsymmetrical functionalizations at the 1,7-positions. The optical properties of the unsymmetrical PDI derivative were reported and compared with those of the symmetrical derivative.Image for unlabelled figure